Green synthesis and antitumor activity of ()-diethyl 2-styrylquinoline-3,4-dicarboxylates.

In this work, a green, efficient and catalyst-free synthesis of a series of structurally novel ()-diethyl 2-styrylquinoline-3,4-dicarboxylates a direct olefination reaction between diethyl 2-methylquinoline-3,4-dicarboxylate and various aromatic aldehydes was successfully accomplished by employing eco-friendly 1,3-dimethylurea/l-(+)-tartaric acid (DMU/LTA) as an inexpensive, non-toxic and reusable reaction medium. This methodology has the attractive advantages of mild reaction conditions, simple experimental operation, and the absence of any dangerous catalysts or unsafe volatile organic solvents, with satisfactory to good yields. Subsequently, a primary evaluation for their anti-proliferative activity against human cancer cell lines A549, HT29 and T24 revealed that the compound with the 3,4,5-trimethoxystyryl moiety exhibited potent anti-tumor activity with IC values of 2.

A Flexible MXene-Black Phosphorus/Zinc Oxide Hybrid Structure with Excellent UVA-Specific Photoelectric Sensing Properties for Human Skin Protection.

Ultraviolet A (UVA) radiation causes various irreversible damages to human skin, so the research about UVA-specific sensing device is urgent. 2D black phosphorus (BP) is used in many photosensors due to its advantages of high carrier mobility and tunable bandgap, but its application for UVA-specific photosensor is not reported. Here, a MXene-BP/Zinc oxide (ZnO) hybrid structure with lamellar-spherical interfaces like finger lime fruit is prepared by the layer-by-layer assembly (LLA) method, and p-n junctions are constructed between BP and ZnO with the TiCT electrode, showing excellent photoelectric performance.

Spatial Steerability of GANs via Self-Supervision from Discriminator.

Generative models make huge progress to the photorealistic image synthesis in recent years. To enable humans to steer the image generation process and customize the output, many works explore the interpretable dimensions of the latent space in GANs. Existing methods edit the attributes of the output image such as orientation or color scheme by varying the latent code along certain directions.

Filter-Less Color-Selective Photodetector Derived from Integration of Parallel Perovskite Photoelectric Response Units.

Color-selective photodetectors (PDs) play an indispensable role in spectral recognition, image sensing, and other fields. Nevertheless, complex filters and delicate optical paths in such devices significantly increase their complexity and size, which subsequently impede their integration in smart optoelectronic chips for universal applications. This work demonstrates the successful fabrication of filter-less color-selective perovskite PDs by integrating three perovskite units with different photoresponse on a single chip.

A Multistate Non-Volatile Photoelectronic Memory Device Based on Ferroelectric Tunnel Junction with Modulable Visible Light Photoresponse.

Recently, certain ferroelectric tunnel junctions (FTJs) exhibit non-volatile modulations on photoresponse as well as tunneling electroresistance (TER) effects related to ferroelectric polarization states. From the opposite perspective, the corresponding polarization states can be read by detecting the levels of the photocurrent. In this study, we fabricate a novel amorphous selenium (a-Se)/PbZrTiO (PZT)/Nb-doped SrTiO (NSTO) heterojunction, which exhibits a high TER of 3 × 10.

Ultrasound Induces Local Disorder of FeOOH on CdInS Photoanode for High Efficiency Photoelectrochemical Water Oxidation.

The regulation of the crystal structure of oxygen evolution cocatalyst (OEC) is a promising strategy for enhancing the photoelectrochemical efficiency of photoanodes. However, the prevailing regulating approach typically requires a multistep procedure, presenting a significant challenge for maintaining the structural integrity and performance of the photoanode. Herein, FeOOH with a local disordered structure is directly grown on a CdInS (CIS) photoanode via a simple and mild sonochemical approach.

Sonochemical regulation of oxygen vacancies for BiWO nanosheet-based photoanodes to promote photoelectrochemical performance.

Integration of oxygen vacancies (Vo) into nanostructured semiconductor-based photocatalysts has been recognized as a promising strategy for enhancing the performance of photoelectrochemical (PEC) water splitting. However, precisely controlling the Vo concentration in photocatalysts an effective and tunable approach remains challenging. Herein, a series of optimized bismuth tungstate (BiWO) nanosheet-based photoanodes with varying concentrations of Vo were prepared by a sonochemical method with cavitation detection, which enables accurate manipulation of the acoustic cavitation intensity applied to the surface of BiWO photoanodes in alkaline solution.

Switchable terahertz orbital angular momentum Bessel beams based on spin-decoupled multifunctional reflective metasurfaces.

In this study, switchable terahertz (THz) multi-orbital angular momentum (OAM) Bessel beams (BBs) were developed based on a spin-decoupled reflective multifunctional metasurface (MTS). Switchability was achieved by switching the feed between left-hand circular polarization (LCP), right-hand circular polarization (RCP), and linear polarization (LP) incidences. A switchable physical model was established for calculating the beam direction, OAM mode, polarization, and non-diffractive distance of the outgoing BBs.

In-situ observation of phase separation dynamics for immiscible aqueous solution within ultrasonic field.

A high-speed imaging technique was used to observe the phase separation process of water (HO)-20 %succinonitrile (SCN) immiscible solution within ultrasound field. Combining with numerical simulation, the effects of ultrasonic cavitation and acoustic streaming on the fragmentation and migration of secondary droplets were revealed. It was found that the previously spherical or near-spherical secondary HO-rich droplets formed under static condition were dynamically transformed into several novel forms, such as tadpole-like, string-beads, gourd-like, and threadlike patterns.

Self-Powered Wavelength-Dependent Dual-Polarity Response Photodetector Based on CdS@PEDOT:PSS@Au Sandwich-Structured Core-Shell Nanorod Arrays.

Self-powered operation and multifunctionality have significantly oriented the development of photodetectors (PDs), which could be realized through nanoarchitecture construction and energy band structure design. Herein, a self-powered wavelength-dependent dual-polarity response PD based on (CdS@PEDOT:PSS@Au) sandwich-structured core-shell nanorod arrays (NRAs) is proposed. The synthesis approach of this three-layer heterostructure consists of a hydrothermal reaction, spin coating, and thermal evaporation.

IFKD: Implicit field knowledge distillation for single view reconstruction.

In 3D reconstruction tasks, camera parameter matrix estimation is usually used to present the single view of an object, which is not necessary when mapping the 3D point to 2D image. The single view reconstruction task should care more about the quality of reconstruction instead of the alignment. So in this paper, we propose an implicit field knowledge distillation model (IFKD) to reconstruct 3D objects from the single view.

Ultrasonic Field Induces Better Crystallinity and Abundant Defects at Grain Boundaries to Develop CuS Electromagnetic Wave Absorber.

Ultrasonic field (USF) is widely used to regulate the intrinsic properties of materials that are not applied in electromagnetic wave (EMW) absorption. One reason is that the lack of a response mechanism for the materials to USF hinders the expansion of their EMW absorption performance. Therefore, to address this issue, a series of CuS nanoparticles with diverse anions are constructed in the presence or absence of USF.

Diversity and Biocontrol Potential of Endophytic Fungi and Bacteria Associated with Healthy Welsh Onion Leaves in Taiwan.

Foliar diseases caused by and species are among the major biotic factors limiting Welsh onion production in Taiwan. Owing to concerns about the environment and the development of pathogen resistance to existing fungicides, biological control using endophytes is emerging as an eco-friendly alternative to chemical control. The aim of the present study was to isolate endophytes from healthy Welsh onion leaves and investigate their antagonistic potential against the major phytopathogenic fungi associated with Welsh onion plants in Taiwan.

Vicinity Vision Transformer.

Vision transformers have shown great success on numerous computer vision tasks. However, their central component, softmax attention, prohibits vision transformers from scaling up to high-resolution images, due to both the computational complexity and memory footprint being quadratic. Linear attention was introduced in natural language processing (NLP) which reorders the self-attention mechanism to mitigate a similar issue, but directly applying existing linear attention to vision may not lead to satisfactory results.

Video-based Person re-identification with parallel correction and fusion of pedestrian area features.

Deep learning has provided powerful support for person re-identification (person re-id) over the years, and superior performance has been achieved by state-of-the-art. While under practical application scenarios such as public monitoring, the cameras' resolutions are usually 720p, the captured pedestrian areas tend to be closer to 128×64 small pixel size. Research on person re-id at 128×64 small pixel size is limited by less effective pixel information.

Improved Dual-Polarity Response via Pyro-phototronic Effect for Filterless Visible Light Communication.

Dual-polarity response photodetectors (PDs) take full advantage of the directivity of the photocurrent to identify optical information. The dual-polarity signal ratio, a key parameter that represents the equilibrium degree of responses to different lights, is proposed for the first time. The synchronous enhancement of dual-polarity photocurrents and the amelioration of the dual-polarity signal ratio are beneficial to the practical applications.

A high-temperature acoustic field measurement and analysis system for determining cavitation intensity in ultrasonically solidified metallic alloys.

A high-temperature acoustic field measurement and analysis system (HTAFS) was self-designed and developed to achieve real-time acoustic field analysis and quantitative cavitation characterization within high-temperature liquids. The acoustic signal was acquired by a high-temperature resistant waveguide and calibrated by separate compensation of line and continuous spectra to eliminate frequency offsets. Moreover, a new method was proposed to derive from the continuous-spectrum sound intensity and line-spectrum sound intensity in the frequency band above 1.

Scalable fabrication of self-assembled GeSn vertical nanowires for nanophotonic applications.

In this work, scalable fabrication of self-assembled GeSn vertical nanowires (NWs) based on rapid thermal annealing (RTA) and inductively coupled-plasma (ICP) dry etching was proposed. After thermal treatment of molecular-beam-epitaxy-grown GeSn, self-assembled Sn nanodots (NDs) were formed on surface and the spontaneous emission from GeSn direct band was enhanced by ∼5-fold. Employing the self-assembled Sn NDs as template, vertical GeSn NWs with a diameter of 25 ± 6 nm and a density of 2.

Effects of increasing chlorine concentration in feedstock on the emission and distribution characteristic of dioxins in circular fluidized bed boiler.

Field studies were conducted to study the emission and distribution characteristics of dioxins by elevating the chlorine concentration in feedstock in a circular fluidized bed boiler. The concentration and total equivalent quantity of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) in all flue gas, electrostatic ash, bag filter ash, and bottom ash samples under blank condition (i.e.

MEMS ultrasonic transducers for safe, low-power and portable eye-blinking monitoring.

Eye blinking is closely related to human physiology and psychology. It is an effective method of communication among people and can be used in human-machine interactions. Existing blink monitoring methods include video-oculography, electro-oculograms and infrared oculography.

Constructing a High-Quality t-Se/Si Interface Via In Situ Light Annealing of a-Se for a Self-Powered Image Sensor.

The quality of the interface, e.g., the semiconductor-semiconductor or metal-semiconductor interface, is the main factor restricting the photodetection performance of a heterojunction.

Circular Photogalvanic Effect in Oxide Two-Dimensional Electron Gases.

Two-dimensional electron gases (2DEGs) at the LaAlO_{3}/SrTiO_{3} interface have attracted wide interest, and some exotic phenomena are observed, including 2D superconductivity, 2D magnetism, and diverse effects associated with Rashba spin-orbit coupling. Despite the intensive investigations, however, there are still hidden aspects that remain unexplored. For the first time, here we report on the circular photogalvanic effect (CPGE) for the oxide 2DEG.

What is the better choice for nurses? Alternating air pressure mattresses versus static air mattresses to prevent pressure ulcers in elderly hospitalized patients: A protocol for systematic review and meta-analysis.

Background: Evidence on the comparative effectiveness between commercially available support surfaces in preventing pressure ulcer development is lacking. The purpose of this study was to compare the efficacy and safety of alternating air pressure mattresses (AAPMs) versus static air mattresses to prevent pressure ulcers in elderly hospitalized patients and to provide evidence for clinical practice.

Methods: The electronic databases of Cochrane Library, EMBASE, PubMed, and Web of Science will be searched in April 2022 using the following key terms: "pressure ulcers," "support surface," and "pressure mattresses," for all relevant studies.

Occurrence and formation pathways analysis of PBDD/Fs from 2,4,6-tribromophenol under thermal reaction conditions.

Polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) are highly toxic and persistent compounds that provoke a wave of publicity. Bromophenols are important precursors for forming PBDD/Fs, and their reaction path has always been a research hotspot. In this study, the formation characteristic of PBDD/Fs from 2,4,6-TBP were studied.