The bio-inspired honeycomb column thin-walled structure (BHTS) is inspired by the biological structure of beetle elytra and designed as a lightweight buffer interlayer to prevent damage to the reinforced concrete bridge pier (RCBP) under the overload impact from vehicle impact. According to the prototype structure of the pier, a batch of scale models with a scaling factor of 1:10 was produced. The BHTS buffer interlayer was installed on the reinforced concrete (RC) column specimen to carry out the steel ball impact test.
View Article and Find Full Text PDFThe existence state and spatiotemporal evolution process of uranium in mineral-microbe complex systems are important factors that constrain its ecotoxicity. This study investigated the sequestration of U(VI) by montmorillonite-Aspergillus niger (MTA) composite using bioassay and spectroscopies approaches. The results demonstrate that the sequestration process and mechanism of U(VI) on MTA differ substantially from those of individual components.
View Article and Find Full Text PDFHigh ammonia concentration inhibits archaea's activity, causing the accumulation of H and acetate, which suppresses methane production in anaerobic digestion (AD). The study aimed to enhance microbial hydrogen metabolism through a side-stream hydrogen domestication (SHD) strategy, which involves applying hydrogen stimulation to a portion of the sludge separately. SHD maintained a stable methane yield of 407.
View Article and Find Full Text PDFBiochar-supported iron-containing minerals have received much attention due to their synergistic mechanism of decontamination in environmental pollution remediation. In this work, two types of iron/biochar were prepared from different biomasses using ferric chloride as the Fe source and rice husks and peanut shell as biomasses. The formation of fayalite (FeSiO) and magnetite (FeO) in rice husk and peanut shell derived biochar was proved by X-ray diffraction.
View Article and Find Full Text PDFThe photocatalytic U(VI) reduction is regarded as an effective strategy for recovering uranium. However, its application in seawater uranium extraction poses challenges due to limited reactivity in the presence of carbonate and under atmospheric conditions. In the present study, a photoactive hydrogel made of carboxyl-functionalized g-CN/CdS (CCN/CdS) is designed for extracting uranium.
View Article and Find Full Text PDFBiochar has attracted significant attention due to its excellent environmental benefits and extensive applications. Recently, a consensus has been accepted that biochar can act as a photocatalyst and trigger effective photocatalytic reactions in the environment, which is important to energy conversion and the cycle of elements. However, its photocatalytic processes and the corresponding environmental impacts need to receive more and due attention.
View Article and Find Full Text PDFIn this study, a series of biochar were prepared via pyrolyzing cellulose-rich pakchoi (PBC) and lignin-rich corncob (CBC) to explore the photoreduction process of Cr(VI). X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy confirmed higher oxygenated functional groups in PBC (48.9%-57.
View Article and Find Full Text PDFA novel photo-Fenton catalyst α-FeO@g-CN@NH-MIL-101(Fe) (FGN) with dual Z-scheme heterojunction was successfully prepared by hydrothermal method to degrade tetracycline (TC). The preparation conditions were optimized by orthogonal test, and the successful synthesis was confirmed by characterization analyses. The prepared FGN showed better light absorption performance, higher photoelectrons-holes separation efficiency, lower photoelectrons transfer resistance, and higher specific surface area and pore capacity compared with α-FeO@g-CN and α-FeO.
View Article and Find Full Text PDFThe environmental behavior of radioactive cesium (RCs) in contaminated areas is generally governed by soil and sediment components and natural weathering conditions. In this study, desorption tests and spectroscopic approaches were used to explore the interaction between the weathering of micaceous minerals (i.e.
View Article and Find Full Text PDFPhytoremediation of total petroleum hydrocarbons (TPHs) contamination is a process that uses the synergistic action of plants and rhizosphere microorganisms to degrade, absorb and stabilize pollutants in the soil, and has received increasing attention in recent years. However, this technology still has some challenges under certain conditions (e.g.
View Article and Find Full Text PDFLegumes establish symbioses with rhizobia by forming nitrogen-fixing nodules. Nitrate is a major environmental factor that affects symbiotic functioning. However, the molecular mechanism of nitrate-induced nodule senescence is poorly understood.
View Article and Find Full Text PDFAntioxidants (Basel)
December 2022
In this study, the cytotoxicity and toxic mechanism of carbon quantum dots (CQDs) to were evaluated in vitro. The synthetic CQDs were extremely small in size (~2.08 nm) and displayed strong fluorescence.
View Article and Find Full Text PDFInvestigate the effect of soil organic matter (SOM) and low molecular weight organic acids (LMWOAs) on minerals adsorption of PAHs. Batch adsorption experiments have been carried out to study the adsorption of PAHs (Naphthalene (NaP), Phenanthrene (Phe) and Pyrene (Pyr)) by minerals (Montmorillonite (Mnt), kaolinite (Kln) and calcite (Cal)). This research found that compared with Kln and Cal, Mnt showed the maximum adsorption capability for PAHs.
View Article and Find Full Text PDFThe photocatalytic conversion of soluble U(VI) into insoluble U(IV) is a robust strategy to harvest aqueous uranium, but remains challenging owing to the intermittent availability of solar influx and reoxidation of U(IV) without illumination. Herein, a dual platform based on K and cyano group co-decorated poly(heptazine imide) (K-CN-PHI) is reported that can drive persistent U(VI) extraction upon/beyond light. K-CN-PHI achieves the photocatalytic reduction of U(VI) with a reaction rate of 0.
View Article and Find Full Text PDFPetroleum contamination surrounding oilfields has attracted more concerns. However, the levels, distribution and source of petroleum of Changqing Oilfield soil still remain lots of knowns, which is important for local environmental protection. Given soil contamination issues in Changqiong Oilfield were investigated.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
November 2022
The adsorption behaviors of cellulose and lignin biochar depend on the evolution of their oxygen-containing groups to some extent. In this study, cellulose-rich pakchoi and lignin-rich corncob were selected to prepare the pyrolytic biochar at variable temperatures, named PBC and CBC, respectively. Their structure-function relationships were in-depth studied via the combination of the adsorption experiments of U(VI) and comprehensive spectral analyses.
View Article and Find Full Text PDFThe environmental behaviors of uranium closely depend on its interaction with natural minerals. Ferrihydrite widely distributed in nature is considered as one main natural media that is able to change the geochemical behaviors of various elements. However, the semiconductor properties of ferrihydrite and its impacts on the environmental fate of elements are sometimes ignored.
View Article and Find Full Text PDFThe interaction behaviors of heavy metals and micaceous minerals are extremely important to understand the environmental behaviors of heavy metals. In this work, the interaction behaviors of Cr(VI) and biotite in the presence and absence of HA were studied combining batch and spectroscopic approaches. Batch experiments showed that biotite had the ability to remove Cr(VI) from the water and the removal markedly increased with decreasing pH.
View Article and Find Full Text PDFThe regulation effect of Aspergillus niger to the sorption behavior of U(VI) on kaolinite and illite was studied through investigating the enrichment of U(VI) on kaolinite-Aspergillus niger and illite-Aspergillus niger composites. Kaolinite- or illite-A. niger composites were prepared through co-culturation method.
View Article and Find Full Text PDFCarbonic anhydrase (CA) plays a vital role in photosynthetic tissues of higher plants, whereas its non-photosynthetic role in the symbiotic root nodule was rarely characterized. In this study, 13 CA genes were identified in the model legume by comparison with Arabidopsis CA genes. Using qPCR and promoter-reporter fusion methods, three previously identified nodule-enhanced CA genes (, , and ) have been further characterized, which exhibit different spatiotemporal expression patterns during nodule development.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
December 2021
A novel composite (nZVI/Pd-AC) was prepared by loading nanoscale zero-valent iron (nZVI) and Pd on activated carbon (AC) electrode under electrodeposition with ultrasound, which was used to reductive degradation of methylene blue (MB). The loading contents of Fe and Pd in composite materials were 15.84% and 2.
View Article and Find Full Text PDFThe biological and environmental toxicity of graphene and graphene derivatives have attracted great research interest due to their increasing applications. However, the cytotoxic mechanism is poorly understood. Here, we investigated the cytotoxic effect of graphene oxide nanoribbons (GORs) on () in an in vitro method.
View Article and Find Full Text PDFBackground: Mounting evidence indicates that circular RNAs (circRNAs) participate in the occurrence and development of various diseases, including osteoarthritis (OA). However, the effects and molecular mechanism of circ_0128846 in OA have not been reported.
Methods: The expression levels of circ_0128846, microRNA-127-5p (miR-127-5p), and nicotinamide phosphoribosyltransferase (NAMPT) were determined by quantitative real-time polymerase chain reaction (qRT-PCR) or western blot assay.