Aim: In order to better understand the incidence of IBD in China, we conducted a retrospective study to analyze the clinical information of IBD patients in Shanghai, China.
Methods: From January 2014 to December 2021, patients diagnosed with IBD and hospitalized were enrolled. The demographic, clinical features, symptoms, laboratory tests and treatment data of the patients were retrospectively analyzed.
This work reports boron and oxygen dual-doped carbon nitride nanotubes (B/O-CNNTs) prepared via a copolymerization process for electrocatalytic ammonia synthesis from nitrogen gas (NRR) and nitrate (NORR) sources, respectively. By adjusting the dosage of boron oxide precursor, the texture and content of B/O dual dopants and the coordination environment in the resulting 1D CNNTs can be tuned. The best B/O-CNNTs can achieve maximum Faradaic efficiencies of 35% and 96% at -1.
View Article and Find Full Text PDFExcessive use of nitrogen fertilizer can degrade the quality of wheat grain, while appropriate use of organic fertilizer can enhance starch quality. To clarify the effects of chemical fertilizer and organic fertilizer on wheat quality. We measured indicators such as amylose content, starch granules, starch structure, gelatinization characteristics, and rheological properties of wheat under different proportions of combined application of organic fertilizer and chemical fertilizer, revealing the effects of combined application of organic fertilizer and chemical fertilizer on the physicochemical properties and structure of starch.
View Article and Find Full Text PDFIonic conductive cellulose hydrogels are some of the most promising candidates for flexible sensors. However, it is difficult to simultaneously prepare cellulose hydrogels with high mechanical strength, good ionic conductivity, and antifreeze performance. In this work, a natural clay (attapulgite)-reinforced cellulose hydrogel was fabricated.
View Article and Find Full Text PDFExquisitely tailoring the morphologies of photocatalysts could achieve high activities. In this study, the morphological transformation of bismuth oxyhalide (BiOX, X = Br, I and Cl) from disordered lamellae to regular flowers was facilely achieved via the use of carboxylated cellulose-derived carbon (CDC). The sphere-like structure and abundant surface functional groups of CDC induce the formation of such flower-like morphologies of BiOX/CDC, and this morphology results in a pronounced increase in surface area (e.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
Two-dimensional (2D) heterostructure materials, incorporating the collective strengths and synergetic properties of individual building blocks, have attracted great interest as a novel paradigm in electrode materials science. The family of 2D transition metal carbides and nitrides (e.g.
View Article and Find Full Text PDFBiomass-based hydrogels have become a research hotspot because of their better biocompatibility. However, the preparation of biomass hydrogels is complicated, and they often need to be modified by introducing other substances. In this study, corncob pretreated with bisulfite (125-185 °C) was used as a raw material to prepare lignocellulose hydrogels.
View Article and Find Full Text PDFDeep eutectic solvents (DESs) hold great potential in biorefining because they can efficiently deconstruct the recalcitrant structure of lignocellulose. In particular, inorganic salts with Lewis acids have been proven to be effective at cleaving lignin-carbohydrate complexes. Herein, a Zr-based DES system composed of metal chloride hydrate (ZrOCl·8HO) and ethylene glycol (EG) was designed and used for poplar powder pretreatment.
View Article and Find Full Text PDFWith the rapid development of clinical diagnosis and treatment, many traditional and conventional diagnosis technologies are unable to meet the demands of clinical medicine development. In this situation, nanomaterials are rapidly developing and widely used in the field of diagnosis. Nanomaterials have distinct size-dependent physical or chemical properties, and their optical, magnetic, electrical, thermal, and biological properties can be modulated at the nanoscale by changing their size, shape, chemical composition, and surface functional groups, particularly because they have a larger specific surface area than macromaterials.
View Article and Find Full Text PDFObjective: The tumor, node and metastasis stage is widely applied to classify lung cancer and is the foundation of clinical decisions. However, increasing studies have pointed out that this staging system is not precise enough for the N status. In this study, we aim to build a convenient survival prediction model that incorporates the current items of lymph node status.
View Article and Find Full Text PDFMetal-organic framework derived materials received a lot of attention due to their significant benefits in photocatalytic reactions. In this work, a Z-scheme ZnInS/BiS hierarchical heterojunction is first developed by a one-pot method using CAU-17 as a template. The specific preparation method endows an intimate interface contact between these two monomers, and CAU-17-derived BiS possesses a high surface area and porosity, resulting in an efficient charge separation and O capture.
View Article and Find Full Text PDFIn this work, an intramolecular carbon nitride (CN)-based quaternary homojunction functionalized with pyridine rings is prepared via an in situ alkali-assisted copolymerization strategy of bulk CN and 2-aminopyridine for efficient visible light hydrogen generation. In the obtained structure, triazine-based CN (TCN), heptazine-based CN (HCN), pyridine unit incorporated TCN, and pyridine ring inserted HCN constitute a special multicomponent system and form a built-in electric field between the crystalline semiconductors by the arrangement of energy band levels. The electron-withdrawing function of the conjugated heterocycle can trigger the skeleton delocalization and edge induction effect.
View Article and Find Full Text PDFObjective: The fecal microbiota was studied in patients with inflammatory bowel disease (IBD), and the characteristics of gut microbiota were compared among patients with different subtypes and stages of IBD, aiming to identify the gut microbiota associated with IBD.
Methods: Fecal samples were collected from 41 IBD patients (18 patients with ulcerative colitis [UC] and 23 patients with Crohn's disease [CD]) in the Department of Gastroenterology of East China Hospital, Fudan University between January 2021 and January 2022. In addition, fecal samples were collected from 20 healthy volunteers.
A cellulose-reinforced eutectogel was constructed by deep eutectic solvent (DES) and cotton linter cellulose. Cellulose was dispersed in the ternary DES consisting of acrylic acid, choline chloride and AlCl·6HO. The photoinitiator was then introduced into the system to in situ polymerize acrylic acid monomer to form transparent and ionic conductive eutectogels while keeping all the DES.
View Article and Find Full Text PDFA kind of ionic conductive gel (also named eutectogel) is developed from an inorganic salt (ZnCl)-based deep eutectic solvent (DES). The ternary DES consists of ZnCl, acrylic acid, and water, and cotton linter cellulose is introduced into the DES system to tailor its mechanical and conductive properties. Enabled by the extensive hydrogen bonds and ion-dipole interactions, the obtained eutectogel displays superior ionic conductivity (0.
View Article and Find Full Text PDFObjective: Ulcerative colitis (UC), a chronic and refractory nonspecific inflammatory bowel disease, affects millions of patients worldwide and increases the risk of colorectal cancer. Teprenone is an acylic polyisoprenoid that exerts anti-inflammatory properties in rat models of peptic ulcer disease. This and study was designed to investigate the effects of teprenone on UC and to explore the underlying mechanisms.
View Article and Find Full Text PDFZeolitic imidazolate frameworks (ZIFs) bearing rich accessible Lewis acidic/basic active sites and hierarchical pores are favorable to catalyze the cycloaddition of CO and epoxides with high yields of the target product under mild conditions. In this context, a facile etching and regrowth method is developed here to convert unstable leaf-like zinc-based ZIF-L to one kind of bimetallic ZIF (namely, ZnFe-ZIF) with a rough surface, a porous and accessible three-dimensional structure, and abundant Lewis acidic sites. Owing to the high Fe-doping content functioning as rich Lewis acidic sites and the high CO adsorbing capability together with the structural advantages to favor the mass diffusion, the yield of target cyclic carbonate can be up to >99% for the cycloaddition of CO and epichlorohydrin by ZnFe-ZIF at 6 h under mild conditions (0.
View Article and Find Full Text PDFThis work reports a dual heterojunction of etched MIL-68(In)-NH (MN) supported heptazine-/triazine-based carbon nitride (HTCN) via a facile hydrothermal process for photocatalytic ammonia (NH ) synthesis. By applying the hydrothermal treatment, MN microrods are chemically etched into hollow microtubes, and HTCN with nanorod array structures are simultaneously tightly anchored on the outside surface of the microtubes. With the addition of 9 wt% HTCN, the resulting dual heterojunction presents an enhanced photocatalytic ammonia yield rate of 5.
View Article and Find Full Text PDFHydrogels are emerging materials for solar steam generation to alleviate water scarcity. Herein, a semiconductor of copper sulfide (CuS) was integrated into cellulose hydrogel to fabricate a solar steam evaporator. Sustainable and low-cost cotton linter (cellulose) was regenerated by NaOH/urea solvent.
View Article and Find Full Text PDFMedicine (Baltimore)
August 2023
This study aimed to investigate the characteristics of intestinal flora in patients with chronic functional constipation before and after lactulose intervention. Twenty-nine patients with constipation in the treatment group received oral lactulose (15 mL/d) for a month. Twenty healthy subjects served as controls.
View Article and Find Full Text PDFThe development of next-generation high-capacity freestanding materials as electrodes in lithium-ion batteries (LIBs) has significant potential. Here, oxygen vacancy-rich ZnO (O-ZnO) deposited on carbonized bacterial cellulose (CBC) aerogels is developed via in-situ uniformly growing ZIF-8-NH particles on CBC aerogels, followed by the hydrazine reduction and pyrolysis. The CBC serves as a free-standing skeleton to disperse and support ZIF-8-NH derived ZnO while the introduction of oxygen vacancies can effectively promote the internal ion/electron transfer.
View Article and Find Full Text PDFCellulose-based ionic conductive hydrogels (ICHs) have found extensive applications in flexible electronics and multifunctional sensors. However, simultaneous realization of sufficient conductivity, superior mechanical property and extreme environment tolerance for ICHs remains to be a huge challenge. In this work, a facile one-pot approach was developed to fabricate ICHs by directly dissolving cotton linter cellulose and polyvinyl alcohol (PVA) in a concentrated ZnCl solution.
View Article and Find Full Text PDFThe delicate design of photocatalyst monoliths is of great significance for the practical applications of artificial photocatalysis. An in-situ synthesis to prepare ZnInS/cellulose foam was developed. Cellulose is dispersed in a highly concentrated ZnCl aqueous solution to prepare Zn/cellulose foam.
View Article and Find Full Text PDF