d-Band Holes React at the Tips of Gold Nanorods.

Reactive hot spots on plasmonic nanoparticles have attracted attention for photocatalysis as they allow for efficient catalyst design. While sharp tips have been identified as optimal features for field enhancement and hot electron generation, the locations of catalytically promising d-band holes are less clear. Here we exploit d-band hole-enhanced dissolution of gold nanorods as a model reaction to locate reactive hot spots produced from direct interband transitions, while the role of the plasmon is to follow the reaction optically in real time.