Quantum mechanical effects in plasmonic sub-nanometer cavities formed by a tip and substrate structure.

Enhancing local field intensity through light field compression is one of the core issues in surface plasmon-enhanced spectroscopy. The theoretical framework for the nanostructure composed of a tip and a substrate has predominantly relied on classical electromagnetic models, ignoring the electron tunneling effect. In this paper, we investigate the plasmonic near-field characteristics in the sub-nanometer cavity formed by the tip and the substrate using a quantum-corrected model.

Surface-enhanced photoluminescence and Raman spectroscopy of single molecule confined in coupled Au bowtie nanoantenna.

Optical nanoantennas possess broad applications in the fields of photodetection, environmental science, biosensing and nonlinear optics, owing to their remarkable ability to enhance and confine the optical field at the nanoscale. In this article, we present a theoretical investigation of surface-enhanced photoluminescence spectroscopy for single molecules confined within novel Au bowtie nanoantenna, covering a wavelength range from the visible to near-infrared spectral regions. We employ the finite element method to quantitatively study the optical enhancement properties of the plasmonic field, quantum yield, Raman scattering and fluorescence.

Biobased Composites with High Lignin Content and Excellent Mechanical Properties toward the Ingenious Photoresponsive Actuator.

The fabrication of biobased smart materials from renewable biomasses is of great importance for sustainable development. Although lignin possesses photothermal conversion potential, the development of lignin-based actuators with large contraction and fast photoresponse has various hurdles. Herein, simply by blending with castor oil-derived polyamide elastomers, a lignin-based photoresponsive actuator can be obtained, which accomplishes up to 18% light-driven contraction under loading within 3 s.