Extreme Optical Chirality from Plasmonic Nanocrystals on a Mirror.

Metal nanocrystals synthesized in achiral environments usually exhibit no chiroptical effects. However, by placing nominally achiral nanocrystals 1.3 nm above gold films, we find giant chiroptical effects, reaching anisotropy factors as high as ≈ 0.

Hydrogen Sulfide-Triggered Artificial DNAzyme Switches for Precise Manipulation of Cellular Functions.

The development of synthetic molecular tools responsive to biological cues is crucial for advancing targeted cellular regulation. A significant challenge is the regulation of cellular processes in response to gaseous signaling molecules such as hydrogen sulfide (HS). To address this, we present the design of Gas signaling molecule-Responsive Artificial DNAzyme-based Switches (GRAS) to manipulate cellular functions via HS-sensitive synthetic DNAzymes.

Towards high-performance polarimeters with large-area uniform chiral shells: a comparative study on the polarization detection precision enabled by the Mueller matrix and deep learning algorithm.

Polarization detection and imaging technologies have attracted significant attention for their extensive applications in remote sensing, biological diagnosis, and beyond. However, previously reported polarimeters heavily relied on polarization-sensitive materials and pre- established mapping relationships between the Stokes parameters and detected light intensities. This dependence, along with fabrication and detection errors, severely constrain the working waveband and detection precision.

Origination of the chiroptical effect in plasmonic nano-structures in the view of quasi-normal mode theory.

General chiroptical effects describe all of the interaction differences between light carrying opposite spins and chiral matters, such as circular dichroism, optical activity, and chiral Raman optical activity, and have been proven to hold great promise for extensive applications in physics, chemistry, and biology. However, the underlying physical mechanism is usually explained intangibly by the twisted currents in chiral geometry, where the cross coupling between the electric and magnetic dipoles breaks the degeneracy of the helicity eigenmodes. In this Letter, we construct a clear sight on the origination of the chiroptical effect in the view of the eigenstates of a non-Hermitian system, i.

Metal to insulator transition for conducting polymers in plasmonic nanogaps.

Conjugated polymers are promising material candidates for many future applications in flexible displays, organic circuits, and sensors. Their performance is strongly affected by their structural conformation including both electrical and optical anisotropy. Particularly for thin layers or close to crucial interfaces, there are few methods to track their organization and functional behaviors.

Collagen Anchoring Protein-Nucleic Acid Chimeric Probe for In Situ In Vivo Mapping of a Tumor-Specific Protease.

In situ analysis of biomarkers in the tumor microenvironment (TME) is important to reveal their potential roles in tumor progression and early diagnosis of tumors but remains a challenge. In this work, a bottom-up modular assembly strategy was proposed for a multifunctional protein-nucleic chimeric probe (PNCP) for in situ mapping of cancer-specific proteases. PNCP, containing a collagen anchoring module and a target proteolysis-responsive isothermal amplification sensor module, can be anchored in the collagen-rich TME and respond to the target protease in situ and generate amplified signals through rolling cycle amplification of tandem fluorescent RNAs.

Reflectionless graphene perfect absorber based on parity symmetric unidirectional guided resonance.

We propose a type of reflectionless graphene perfect absorber (GPA) in which the reflection channel is forbidden, while the transmission channel is open. Peak absorption of 99.97% in the near-infrared is numerically demonstrated for monolayer graphene loaded on a one-dimensional silicon photonic crystal slab with rhomboid cross sections that supports parity symmetric unidirectional guided resonances (UGRs).

High quality factor unidirectional guided resonances of a silicon-on-lithium niobate photonic crystal slab for a tunable Gires-Tournois interferometer.

High quality (Q) factor, tunable unidirectional guided resonances (UGRs) based on a silicon-on-lithium niobate (Si-on-LN) photonic crystal (PhC) slab are proposed and numerically investigated. The Q factors of UGRs decay quadratically with respect to the distance from the Γ point to the wave vector along the Γ-X direction, and high Q factor UGRs are obtained by moving UGR close to the Γ point. Also, a Gires-Tournois interferometer (GTI) based on a UGR with a Q factor of 9465 is numerically demonstrated, which produces a maximum group delay of 30 ps around 1.

Full Control of Plasmonic Nanocavities Using Gold Decahedra-on-Mirror Constructs with Monodisperse Facets.

Bottom-up assembly of nanoparticle-on-mirror (NPoM) nanocavities enables precise inter-metal gap control down to ≈ 0.4 nm for confining light to sub-nanometer scales, thereby opening opportunities for developing innovative nanophotonic devices. However limited understanding, prediction, and optimization of light coupling and the difficulty of controlling nanoparticle facet shapes restricts the use of such building blocks.

Spectro-Electrochemistry of Conductive Polymers Using Plasmonics to Reveal Doping Mechanisms.

Conducting polymers are a key component for developing wearable organic electronics, but tracking their redox processes at the nanoscale to understand their doping mechanism remains challenging. Here we present an spectro-electrochemical technique to observe redox dynamics of conductive polymers in an extremely localized volume (<100 nm). Plasmonic nanoparticles encapsulated by thin shells of different conductive polymers provide actively tuned scattering color through switching their refractive index.

FullyPrinted Flexible Plasmonic Metafilms with Directional Color Dynamics.

Plasmonic metafilms have been widely utilized to generate vivid colors, but making them both active and flexible simultaneously remains a great challenge. Here flexible active plasmonic metafilms constructed by printing electrochromic nanoparticles onto ultrathin metal films (<15 nm) are presented, offering low-power electricallydriven color switching. In conjunction with commercially available printing techniques, such flexible devices can be patterned using lithography-free approaches, opening up potential for fullyprinted electrochromic devices.

Effects of Dietary Iron Concentration on Manganese Utilization in Broilers Fed with Manganese-Lysine Chelate-Supplemented Diet.

Dietary iron (Fe) influences manganese (Mn) utilization in chickens fed with inorganic Mn-supplemented diet. This study aimed to determine if dietary Fe levels affect Mn utilization in broilers fed with organic Mn-supplemented diet. Nine hundred 8-day-old broilers were randomly assigned to 1 of 6 treatments in a 3 (Fe level) × 2 (Mn source) factorial arrangement after feeding Mn- and Fe-unsupplemented diets for 7 days.

Effects of Dietary Iron on Manganese Utilization in Broilers Fed with Corn-Soybean Meal Diet.

To investigate the effects of dietary iron (Fe) levels on manganese (Mn) utilization, 900 8-day-old broilers were randomly assigned to 1 of 6 treatments in a 3 (Fe level) × 2 (Mn level) factorial arrangement after feeding Mn- and Fe-unsupplemented diet for 7 days. The broilers were then fed with basal corn-soybean meal diets (approximately 28 mg Mn/kg and 60 mg Fe/kg) added with 0, 80, or 160 mg/kg Fe (L-Fe, M-Fe, or H-Fe), and 0 or 100 mg/kg Mn for 35 days. Body weight gain was lower for H-Fe broilers than that for L-Fe and M-Fe broilers.

Scalable electrochromic nanopixels using plasmonics.

Plasmonic metasurfaces are a promising route for flat panel display applications due to their full color gamut and high spatial resolution. However, this plasmonic coloration cannot be readily tuned and requires expensive lithographic techniques. Here, we present scalable electrically driven color-changing metasurfaces constructed using a bottom-up solution process that controls the crucial plasmonic gaps and fills them with an active medium.

Roll-to-roll fabrication of touch-responsive cellulose photonic laminates.

Hydroxypropyl-cellulose (HPC), a derivative of naturally abundant cellulose, can self-assemble into helical nanostructures that lead to striking colouration from Bragg reflections. The helical periodicity is very sensitive to pressure, rendering HPC a responsive photonic material. Recent advances in elucidating these HPC mechano-chromic properties have so-far delivered few real-world applications, which require both up-scaling fabrication and digital translation of their colour changes.