Guang Pu Xue Yu Guang Pu Fen Xi
June 2007
In the present study, molecular imprinting technique was used to develop a method based on noncovalent interaction for the systhesis of a cotinine-specific polymer. The molecular recognition characteristics of the template polymer were evaluated by UV, IR, XPS and 1H NMR. The results indicated that the interactions should be cooperative hydrogen bonds produced by self-assembling of the template and the monomer.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
October 2006
In the present study, molecular imprinting was used to develop a method based on noncovalent interaction for the synthesis of a monocrotophos-specific polymer. The selective binding characteristics of the template polymer were evaluated by 1H NMR and ultraviolet spectrometry. The polymer obtained was found to interact specifically with monocrotophos by cooperative hydrogen bonding.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
October 2005
The volatile components of clary sage (Salvia sclarea L.) oil were identified by gas chromatography-Fourier transform infrared spectroscopy (GC/FTIR) and gas chromatography-mass spectrometry (GC/MS). The application of GC/FTIR in analysis of essential oil was mainly discussed.
View Article and Find Full Text PDFCotinine, the main metabolite of nicotine in human body, is widely used as a biomarker for assessment of direct or passive exposure to tobacco smoke. A method for molecularly imprinted solid-phase extraction (MISPE) of cotinine from human urine has been investigated. The molecularly imprinted polymer (MIP) with good selectivity and affinity for cotinine was synthesized using cotinine as the template molecule, methacrylic acid as the functional monomer, and ethylene glycol dimethacrylate as the cross-linker.
View Article and Find Full Text PDF