This study investigates the application of levan- produced from Paenibacillus polymyxa SG09-12 as an antiviral agent against cucumber mosaic virus (CMV). A high-purity microbial levan was produced and purified using diafiltration. The chemical composition, structure, and functional groups of the levan were characterised using high-performance liquid chromatography (HPLC), nuclear magnetic resonance (NMR), Fourier-transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS).
View Article and Find Full Text PDFLignin, an abundant natural resource, has not been effectively utilized. In this study, the functionality of lignin was enhanced through amination to produce amine-crosslinked lignin, and its adsorption behavior toward cationic and anionic dyes was investigated. Chemical structure analysis confirmed the successful introduction of amine groups, thereby improving the molecular weight and thermal stability of the optimized amine-crosslinked lignin.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2024
van der Waals heterojunctions utilizing two-dimensional (2D) transition-metal dichalcogenide (TMD) materials have emerged as focal points in the field of optoelectronic devices, encompassing applications in light-emitting devices, photodetectors, solar cells, and beyond. In this study, we transferred few-atomic-layer films of compositionally graded ternary MoSTe alloys onto metal-organic chemical vapor deposition-grown molybdenum disulfide (MoS) as p- and n-type structures, leading to the creation of a van der Waals vertical heterostructure. The characteristics of the fabricated MoSTe/MoS vertical-stacked heterojunction were investigated considering the influence of tellurium (Te) incorporation.
View Article and Find Full Text PDFThe maximum reflection at an open end of a standard rectangular waveguide is about -10 dB in its operating frequency range. It is often used without matching. For critical applications, it is desirable to further reduce the reflection coefficient.
View Article and Find Full Text PDFIn this study, a novel zwitterion-substituted lignin (ZL) containing amino and sulfonic acid groups was synthesized, and ZL/Nafion composite membranes were fabricated as proton exchange membranes. Kraft lignin was modified using an aminosilane and 1,3-propanesultone via a continuous grafting reaction to provide zwitterionic moieties. Chemical structural analyses confirmed the successful introduction of the zwitterion moiety into lignin.
View Article and Find Full Text PDFThe development of eco-friendly, sustainable, biodegradable, and biocompatible green biopolymer composites is becoming increasingly important. In this study, acetoacetylated lignin (ATL) was obtained via an eco-friendly, facile one-step synthesis reaction, and chitosan (CS)-containing ATL films (CSL) were prepared. The chemical structural analysis of ATL confirmed that the acetoacetyl groups were successfully grafted onto kraft lignin (KL).
View Article and Find Full Text PDFResearch on low-cost bio-adsorbents for the removal of harmful substances from effluents has recently attracted significant attention. In this study, three types of amino-silane-modified lignins (ASLs) with primary, secondary, and tertiary amine groups were prepared, and their adsorption behavior toward cationic and anionic dyes was investigated. Chemical structural analyses indicated that the three amino-silane reagents resulted in different molecular self-assembly structures on the lignin surface.
View Article and Find Full Text PDFMultifunctional polymers derived from renewable organic substances have received significant attention. In this work, the Diels-Alder "click" reaction was used to synthesize a renewable copolymer with the mechanical strength of cellulose nanocrystals (CNCs) and the natural antioxidant activity of lignin. Chemical structural analysis and molecular weight results confirmed that lignin was successfully attached to the CNCs.
View Article and Find Full Text PDFCellulose from different lignocellulosic biomass can be used to prepare various materials. In this work, the cellulose nanofibrils were produced from hardwood bleached kraft pulp. Then, a novel biosorbent from cellulose nanofibrils grafted with poly(-aminobenzene sulfonate) (PABS) was prepared for effective detoxification and adsorption of Cr(VI) in an aqueous medium.
View Article and Find Full Text PDFInt J Mol Sci
January 2021
Cancer is the second leading cause of death worldwide, with 9.6 million people estimated to have died of cancer in 2018. Excess body fat deposition is a risk factor for many types of cancer.
View Article and Find Full Text PDFSkeletal muscle atrophy is one of the major symptoms of cancer cachexia. Garlic (), one of the world's most commonly used and versatile herbs, has been employed for the prevention and treatment of diverse diseases for centuries. In the present study, we found that ajoene, a sulfur compound found in crushed garlic, exhibits protective effects against muscle atrophy.
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