Photocatalyzed hydrodecarboxylation of fatty acids: a prospective method to produce drop-in biofuels.

A direct and practical method for photocatalyzed hydrodecarboxylation of fatty acids is reported herein. The catalytic system consists of a commercially available acridinium salt as the photocatalyst and thiophenol as the Hydrogen Atom Transfer (HAT) co-catalyst. Results evidenced that C alkanes were obtained in yields up to 77%.

Photocatalytic Hydrodecarboxylation of Fatty Acids for Drop-in Biofuels Production.

A mild, practical, and environmentally friendly method for the hydrodecarboxylation of fatty acids using an acridine-based photoredox catalyst and thiophenol was developed. C alkanes were synthesized in good to excellent yields (up to 99 %) from C10-C18 saturated fatty acids under visible light irradiation (405 nm). The developed protocol was employed for a mixture of fatty acids obtained from the hydrolysis of Licuri oil, affording a mixture of C9-C17 hydrocarbons in quantitative yield, which demonstrates the potential application of the method to produce drop-in biofuels.

Nickel-catalyzed reductive decarboxylation of fatty acids for drop-in biofuel production.

An operationally simple and highly selective method for the decarboxylation of fatty acids under remarkably mild conditions is described herein. The activation of the aliphatic carboxylic acids by esterification with -hydroxyphthalimide (NHPI) enabled efficient deoxygenation to synthesize -alkanes in up to 67% yield, employing inexpensive PMHS as a hydrogen source, NiCl·6HO, bipyridine, and zinc in THF. In contrast to the conventional thermo-catalytic approaches, this protocol does not require high temperature and high pressure of hydrogen gas to deoxygenate biomass-derived carboxylic acids, thus representing an attractive alternative for producing drop-in biofuels.