The valorization of CO as a biofuel, transforming it through methanation as part of the power-to-gas (P2G) process, will allow the reduction of the net emissions of this gas to the atmosphere. Catalysts with 13 wt.% of nickel (Ni) loading incorporated into alumina and graphene derivatives were used, and the effect of the support on the activity was examined at temperatures between 498 and 773 K and 10 bar of pressure.
View Article and Find Full Text PDFEnergy storage from renewable sources is possible by chemical procedures, power to gas technology being a possible solution for long-term storage. In this work, CO methanation from a sulphur containing gas was studied, taking into account deactivation of the catalysts and a regeneration process. In order to improve the sulphur resistance of a standard nickel (13%) catalyst supported on alumina, transition metals like molybdenum (Mo), iron (Fe), cobalt (Co) or chromium (Cr), in different proportions (from 4 to 8 wt%) were added to the catalyst formulation.
View Article and Find Full Text PDFThermochemical lignin conversion processes can be described as complex reaction networks involving not only de-polymerization and re-polymerization reactions, but also chemical transformations of the depolymerized mono-, di-, and oligomeric compounds. They typically result in a product mixture consisting of a gaseous, liquid (i.e.
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