Adsorption at the Air-Water Interface in Biosurfactant-Surfactant Mixtures: Quantitative Analysis of Adsorption in a Five-Component Mixture.

The composition of the air-water adsorbed layer of a quinary mixture consisting of three conventional surfactants, octaethylene glycol monododecyl ether (CE), dodecane-6-p-sodium benzene sulfonate (LAS6), and diethylene glycol monododecyl ether sodium sulfate (SLES), mixed with two biosurfactants, the rhamnolipids l-rhamnosyl-l-rhamnosyl-β-hydroxydecanoyl-β-hydroxydecanoyl, R2, and l-rhamnosyl-β-hydroxydecanoyl-β-hydroxydecanoyl, R1, has been measured over a range of compositions above the mixed critical micelle concentration. Additional measurements on some of the subsets of ternary and binary mixtures have also been measured by NR. The results have been analyzed using the pseudophase approximation (PPA) in conjunction with an excess free energy, G, that depends on the quadratic and cubic terms in the composition.

Impact of Electrolyte on Adsorption at the Air-Water Interface for Ternary Surfactant Mixtures above the Critical Micelle Concentration.

The composition of the air-water adsorbed layer of the ternary surfactant mixture, octaethylene monododecyl ether, CE, sodium dodecyl 6-benzenesulfonate, LAS, and sodium dioxyethylene glycol monododecyl sulfate, SLES, and of each of the binary mixtures, with varying amounts of electrolyte, has been studied by neutron reflectivity. The measurements were made above the mixed critical micelle concentration. In the absence of electrolyte adsorption is dominated by the nonionic component CE but addition of electrolyte gradually changes this so that SLES and LAS dominate at higher electrolyte concentrations.

Surface Adsorption in Ternary Surfactant Mixtures above the Critical Micelle Concentration: Effects of Asymmetry on the Composition Dependence of the Excess Free Energy.

The composition of the adsorbed layer of a ternary surfactant mixture at the air-water interface has been studied by neutron reflectivity. The adsorption of the ternary mixture of octaethylene monododecyl ether (CE) sodium dodecyl 6-benzene sulfonate (LAS), and sodium dioxyethylene glycol monododecyl sulfate (SLES), as well as each of the binary mixtures, at solution concentrations greater than the mixed critical micelle concentration is highly nonideal. In the ternary mixture, the surface adsorption is dominated by CE and LAS, and there is little SLES at the interface.