Organic phosphates (OP) are important nutrient components for living cells in natural environments, where they readily interact with ubiquitous iron phases such as hydrous ferric oxide, ferrihydrite (FHY). FHY partakes in many key bio(geo)chemical reactions including iron-mediated carbon storage in soils, or iron-storage in living organisms. However, it is still unknown how OP affects the formation, structure and properties of FHY.
View Article and Find Full Text PDFWe undertook Sr/Sr analyses for a range of carbonate bearing geological reference materials, and combined these with δMg for a subset of samples. Following chemical purification in a series of chromatographic extractions, isotope ratios were measured by Multi-Collector-ICP-MS using a Plasma II (Nu instruments, Wrexham, UK). To validate efficient sample digestion procedures of carbonate fractions, total samples were treated with either 3 mol l HNO and 0.
View Article and Find Full Text PDFAmorphous calcium phosphate (Ca(PO)xnHO; n = 3-4.5; ACP) is a precursor phase of the mineral hydroxyapatite (Ca(PO)(OH); HAP) that in natural settings occurs during both authigenic and biogenic mineral formation. In aqueous solutions ACP transforms rapidly to the crystalline phase.
View Article and Find Full Text PDF