Growing a Chemical Garden at the Air-Fluid Interface.

Here we grow chemical gardens using a novel, quasi two-dimensional, experimental configuration. Buoyant calcium chloride solution is pumped onto the surface of sodium silicate solution. The solutions react to form a precipitation structure on the surface.

Spontaneous formation of complex structures made from elastic membranes in an aluminum-hydroxide-carbonate system.

A popular playground for studying chemo-hydrodynamic patterns and instabilities is chemical gardens, also known as silicate gardens. In these systems, complex structures spontaneously form, driven by buoyant forces and either osmotic or mechanical pumps. Here, we report on systems that differ somewhat from classical chemical gardens in that the membranes are much more deformable and soluble.

Cyclic growth of hierarchical structures in the aluminum-silicate system.

Background: Biological structures grow spontaneously from a seed, using materials supplied by the environment. These structures are hierarchical, with the 'building blocks' on each level constructed from those on the lower level. To understand and model the processes that occur on many levels, and later construct them, is a difficult task.

Emergence of complex behavior in chemical cells: the system AlCl₃-NaOH.

Chemical cells that spontaneously form in simple inorganic systems are presented. The cells are surrounded by semipermeable membranes that allow water and some ions to diffuse through. These cells exhibit dynamical behaviors that are typically associated with biological entities.

Temporal and spatial organization of chemical and hydrodynamic processes. The system Pb(2+)-chlorite-thiourea.

Precise spatio-temporal organization of chemical, hydrodynamic, and mechanical processes is typical for biological systems where particular chemical reactions have to accrue in precisely assignment place and time. It is rarely studied and observed in chemical systems. We report unusual precipitation pattern formation of PbSO(4) in chemical media (Pb(2+)-Chlorite-Thiourea System).

Metabolic photofragmentation kinetics for a minimal protocell: rate-limiting factors, efficiency, and implications for evolution.

A key requirement of an autonomous self-replicating molecular machine, a protocell, is the ability to digest resources and turn them into building blocks. Thus a protocell needs a set of metabolic processes fueled by external free energy in the form of available chemical redox potential or light. We introduce and investigate a minimal photodriven metabolic system, which is based on photofragmentation of resource molecules catalyzed by genetic molecules.

Complex morphology in a simple chemical system.

Chemical systems, far from thermodynamic equilibrium, may spontaneously self-construct complex structures mimicking biological structures.

Transverse coupling of chemical waves.

The transverse coupling of chemical waves is investigated using a model scheme for excitable media. Chemical waves supported on the surfaces of a semipermeable membrane couple via diffusion through the membrane, resulting in new types of spatiotemporal behavior. The model studies show that spontaneous wave sources may develop from interacting planar waves, giving rise to a complex sequence of patterns accessible only by perturbation.