Dynamics of Aggregation in Systems of Self-Propelled Rods.

We highlight camphene-camphor-polypropylene plastic as a useful material for self-propelled objects that show aggregation while floating on a water surface. We consider self-propelled rods as an example of aggregation of objects characterized by non-trivial individual shapes with low-symmetry interactions between them. The motion of rods made of the camphene-camphor-polypropylene plastic is supported by dissipation of the surface-active molecules.

Deformation dynamics of an oil droplet into a crescent shape during intermittent motion.

A paraffin droplet containing camphor and oil red O (dye) floating on the water surface shows spontaneous motion and deformation generated by the surface tension gradient around the droplet. We focused on the intermittent motion with a pronounced deformation into a crescent shape observed at specific concentrations of camphor and oil red O. We quantitatively analyzed the time changes in the droplet deformation and investigated the role of the oil red O by measuring the time-dependent paraffin-water interfacial tension with the pendant drop method.

Chemical Memory with Discrete Turing Patterns Appearing in the Glycolytic Reaction.

Memory is an essential element in information processing devices. We investigated a network formed by just three interacting nodes representing continuously stirred tank reactors (CSTRs) in which the glycolytic reaction proceeds as a potential realization of a chemical memory unit. Our study is based on the 2-variable computational model of the reaction.

New types of complex motion of a simple camphor boat.

We discuss the motion of a rectangular camphor boat, considering the position of a camphor pill in relation to the boat's stern as the control parameter. The boat moves because the pill releases surface active molecules that decrease the surface tension and support the motion. We introduce a new experimental system in which the boat rotates on a long arm around the axis located at the centre of a Petri dish; thus, the motion is restricted to a circle and can be studied under stationary conditions for a long time.

Information Processing Using Networks of Chemical Oscillators.

I believe the computing potential of systems with chemical reactions has not yet been fully explored. The most common approach to chemical computing is based on implementation of logic gates. However, it does not seem practical because the lifetime of such gates is short, and communication between gates requires precise adjustment.

Dynamic ordering caused by a source-sink relation between two droplets.

Two droplets composed of different chemicals, 1-decanol and liquid paraffin, floating on the water surface show characteristic co-responsive behavior. The presence of two different types of droplets in the system imposes an asymmetry that would not be possible with single droplets alone. The self-propulsion and interactions between droplets appear because surface active 1-decanol molecules provided by the source are absorbed by the paraffin sink thus generating an asymmetric surface tension gradient.

Complexity and bifurcations in the motion of a self-propelled rectangle confined in a circular water chamber.

We consider the motion of a self-propelled object of rectangular shape inside a circular water chamber. The mathematical model of self-motion includes equations for the orientation and location of the rectangle and reaction-diffusion equation with an effective diffusion coefficient for the time evolution of the surface concentration of active molecules. Numerical simulations of motion were performed for different values of the ratio between the supply rate and the evaporation rate of active molecules.

The Concilium of Information Processing Networks of Chemical Oscillators for Determining Drug Response in Patients With Multiple Myeloma.

It can be expected that medical treatments in the future will be individually tailored for each patient. Here we present a step towards personally addressed drug therapy. We consider multiple myeloma treatment with drugs: bortezomib and dexamethasone.

Computing With Networks of Chemical Oscillators and its Application for Schizophrenia Diagnosis.

Chemical reactions are responsible for information processing in living organisms, yet biomimetic computers are still at the early stage of development. The bottom-up design strategy commonly used to construct semiconductor information processing devices is not efficient for chemical computers because the lifetime of chemical logic gates is usually limited to hours. It has been demonstrated that chemical media can efficiently perform a specific function like labyrinth search or image processing if the medium operates in parallel.

A camphene-camphor-polymer composite material for the production of superhydrophobic absorbent microporous foams.

In a recently published paper (doi.org/10.3390/molecules26113116) on self-propelled motion of objects on the water surface, we described a novel surface-active plastic material obtained by dissolution of camphor and polypropylene in camphene at 250 [Formula: see text]C.

A Perfect Plastic Material for Studies on Self-Propelled Motion on the Water Surface.

We describe a novel plastic material composed of camphene, camphor, and polypropylene that seems perfectly suited for studies on self-propelled objects on the water surface. Self-motion is one of the attributes of life, and chemically propelled objects show numerous similarities with animated motion. One of important questions is the relationship between the object shape and its motility.

Applications of Information Theory Methods for Evolutionary Optimization of Chemical Computers.

It is commonly believed that information processing in living organisms is based on chemical reactions. However, the human achievements in constructing chemical information processing devices demonstrate that it is difficult to design such devices using the bottom-up strategy. Here I discuss the alternative top-down design of a network of chemical oscillators that performs a selected computing task.

How Does a Simple Network of Chemical Oscillators See the Japanese Flag?

Chemical computing is something we use every day (e.g., in the brain), but we can still not explore and master its potential in human-made experiments.

Inversion probability of three-bladed self-propelled rotors after forced stops of different durations.

We investigated self-propelled rotation of a symmetric three-bladed rotor on water under periodic halt and release operations. The rotation was driven by the difference in the surface tension around the blades of the rotor because camphor molecules developed from three camphor disks glued at the blade ends. Spontaneous inversion of rotation direction was observed after a forced stop of the rotor and the subsequent release.

On a simple model that explains inversion of a self-propelled rotor under periodic stop-and-release-operations.

We propose a simple mathematical model that describes the time evolution of a self-propelled object on a liquid surface using variables such as object location, surface concentration of active molecules, and hydrodynamic surface flow. The model is applied to simulate the time evolution of a rotor composed of a polygonal plate with camphor pills at its corners. We have qualitatively reproduced results of experiments, in which the inversion of rotational direction under periodic stop-and-release-operations was investigated.

A hybrid camphor-camphene wax material for studies on self-propelled motion.

A new material that combines the self-propelling properties of camphor with the malleability of camphene is reported. It has wax-like mechanical properties at room temperature and can be formed into required shapes. The speed of the self-propelled objects and the trajectory depend on the shape and camphor-camphene weight ratio.

Bifurcation in the angular velocity of a circular disk propelled by symmetrically distributed camphor pills.

We studied rotation of a disk propelled by a number of camphor pills symmetrically distributed at its edge. The disk was put on a water surface so that it could rotate around a vertical axis located at the disk center. In such a system, the driving torque originates from surface tension difference resulting from inhomogeneous surface concentration of camphor molecules released from the pills.

Method development and validation for total mercury determination in coke oven gas combining a trap sampling method with CVAAS detection.

Coke oven gas is one of the by-products of the coal coking process. It is used as a fuel in the coking plant, but also as a raw material in the chemical industry to produce methanol, syngas or environment-friendly, low-CO hydrogen fuel. Due to the reasons mentioned above, the knowledge of coke oven gas pollutants such as mercury is a key issue.

Period of Oscillatory Motion of a Camphor Boat Determined by the Dissolution and Diffusion of Camphor Molecules.

Here, we investigated the oscillatory motion of a camphor boat on water to clarify how the dynamics of camphor concentration profile determines the period of oscillation. The boat, which was made of a plastic plate and a camphor disk, was glued below the plate at a distance from the edge. The dependence of oscillation period on temperature and viscosity of the water phase was measured in experiments.

Relationship between the size of a camphor-driven rotor and its angular velocity.

We consider a rotor made of two camphor disks glued below the ends of a plastic stripe. The disks are floating on a water surface and the plastic stripe does not touch the surface. The system can rotate around a vertical axis located at the center of the stripe.

Cancer classification with a network of chemical oscillators.

We discuss chemical information processing considering dataset classifiers formed with a network of interacting droplets. Our arguments are based on computer simulations of droplets in which a photosensitive variant of the Belousov-Zhabotinsky (BZ) reaction proceeds. By applying optical control we can adjust the time evolution of individual droplets and prepare the network to perform a specific computational task.

Unidirectional motion of a camphor disk on water forced by interactions between surface camphor concentration and dynamically changing boundaries.

We study the motion of a camphor disk on the water surface in a system with flexible boundaries. The boundaries can be dynamically modified by non-uniform surface tension resulting from the nonhomogeneous surface concentration of the camphor molecules dissipated by the disk. We investigate the geometry of the boundaries that forces unidirectional motion of the disk.

Chemical memory with states coded in light controlled oscillations of interacting Belousov-Zhabotinsky droplets.

The information storing potential of droplets, in which an oscillatory, photosensitive Belousov-Zhabotinsky (BZ) reaction proceeds, is investigated experimentally. We consider coupled oscillations in pairs and triplets of droplets. Droplets are surrounded by a solution of lipids in decane.

Evolutionary Design of Classifiers Made of Droplets Containing a Nonlinear Chemical Medium.

Unconventional computing devices operating on nonlinear chemical media offer an interesting alternative to standard, semiconductor-based computers. In this work we study in-silico a chemical medium composed of communicating droplets that functions as a database classifier. The droplet network can be "programmed" by an externally provided illumination pattern.

Selection of the Rotation Direction for a Camphor Disk Resulting from Chiral Asymmetry of a Water Chamber.

Self-motion of a camphor disk rotating inside a water chamber composed of two half-disks was investigated. The half-disks were joined along their diameter segments, and the distance between their midpoints (ds) was considered as the control parameter. Various types of camphor disk motions were observed depending on ds.