Photophysics of a single quantum emitter based on vanadium phthalocyanine molecules.

Single quantum emitters play a fundamental role in the development of quantum technologies such as quantum repeaters, and quantum information processing. Isolating individual molecules with stable optical emission is an essential step for these applications, especially for those molecules that present large coherence times at room temperature. Among them, vanadium-oxide phthalocyanine (VOPc) molecules stand out as promising candidates due to the large coherence times of their ground state electronic spin, which are on the order of microseconds when measured in the ensemble.

Temperature-Dependent Photophysics of Single NV Centers in Diamond.

We present a comprehensive study of the temperature- and magnetic-field-dependent photoluminescence (PL) of individual NV centers in diamond, spanning the temperature-range from cryogenic to ambient conditions. We directly observe the emergence of the NV's room-temperature effective excited-state structure and provide a clear explanation for a previously poorly understood broad quenching of NV PL at intermediate temperatures around 50 K, as well as the subsequent revival of NV PL. We develop a model based on two-phonon orbital averaging that quantitatively explains all of our findings, including the strong impact that strain has on the temperature dependence of the NV's PL.

Collective enhancement in dissipative quantum batteries.

We study a quantum battery made out of N nonmutually interacting qubits coupled to a dissipative single electromagnetic field mode in a resonator. We quantify the charging energy, ergotropy, transfer rate, and power of the system, showing that collective enhancements are still present despite losses, and can even increase with dissipation. Moreover, we observe that a performance deterioration due to dissipation can be reduced by scaling up the battery size.

Low-Temperature Photophysics of Single Nitrogen-Vacancy Centers in Diamond.

We investigate the magnetic field dependent photophysics of individual nitrogen-vacancy (NV) color centers in diamond under cryogenic conditions. At distinct magnetic fields, we observe significant reductions in the NV photoluminescence rate, which indicate a marked decrease in the optical readout efficiency of the NV's ground state spin. We assign these dips to excited state level anticrossings, which occur at magnetic fields that strongly depend on the effective, local strain environment of the NV center.

Probing Charge Dynamics in Diamond with an Individual Color Center.

Control over the charge states of color centers in solids is necessary to fully utilize them in quantum technologies. However, the microscopic charge dynamics of deep defects in wide-band-gap semiconductors are complex, and much remains unknown. We utilize a single-shot charge-state readout of an individual nitrogen-vacancy (NV) center to probe the charge dynamics of the surrounding defects in diamond.

Sensing Electrochemical Signals Using a Nitrogen-Vacancy Center in Diamond.

Chemical sensors with high sensitivity that can be used under extreme conditions and can be miniaturized are of high interest in science and industry. The nitrogen-vacancy (NV) center in diamond is an ideal candidate as a nanosensor due to the long coherence time of its electron spin and its optical accessibility. In this theoretical work, we propose the use of an NV center to detect electrochemical signals emerging from an electrolyte solution, thus obtaining a concentration sensor.

High-fidelity spin and optical control of single silicon-vacancy centres in silicon carbide.

Scalable quantum networking requires quantum systems with quantum processing capabilities. Solid state spin systems with reliable spin-optical interfaces are a leading hardware in this regard. However, available systems suffer from large electron-phonon interaction or fast spin dephasing.

Functionalization of stable fluorescent nanodiamonds towards reliable detection of biomarkers for Alzheimer's disease.

Background: Stable and non-toxic fluorescent markers are gaining attention in molecular diagnostics as powerful tools for enabling long and reliable biological studies. Such markers should not only have a long half-life under several assay conditions showing no photo bleaching or blinking but also, they must allow for their conjugation or functionalization as a crucial step for numerous applications such as cellular tracking, biomarker detection and drug delivery.

Results: We report the functionalization of stable fluorescent markers based on nanodiamonds (NDs) with a bifunctional peptide.

Electronic structure of the silicon vacancy color center in diamond.

The negatively charged silicon vacancy (SiV) color center in diamond has recently proven its suitability for bright and stable single photon emission. However, its electronic structure so far has remained elusive. We here explore the electronic structure by exposing single SiV defects to a magnetic field where the Zeeman effect lifts the degeneracy of magnetic sublevels.

Diffraction unlimited all-optical recording of electron spin resonances.

We show stimulated emission depletion microscopy to break the diffraction limit in the all-far-field-optical detection of magnetic fields and resonances. Electron spin resonances from single nitrogen-vacancy centers in diamond located at subdiffraction proximities are fully discerned. Since diffraction is overcome by disallowing the signaling state through an optical transition such as stimulated emission, the spin state remains unaffected and amenable to microwave manipulation.