Reactivity Study of Unsymmetrical β-Diketiminato Copper(I) Complexes: Effect of the Chelating Ring.

β-Diketiminato copper(I) complexes play important roles in bioinspired catalytic chemistry and in applications to the materials industry. However, it has been observed that these complexes are very susceptible to disproportionation. Coordinating solvents or Lewis bases are typically used to prevent disproportionation and to block the coordination sites of the copper(I) center from further decomposition.

Preparation and evaluation of the bioinspired PS/PDMS photochromic films by the self-assembly dip-drawing method.

Emulsifier-free emulsion polymerization was employed to synthesize polystyrene (PS) microspheres, which were then self-assembled into an ordered periodic structure. A photochromic film was formed by adding polydimethylsiloxane (PDMS) around the self-assembly of PS microspheres on a PDMS substrate. During polymerization, the PS microspheres shrunk depending on the amount of the hydrophilic comonomer, sodium 4-styrenesulfonate (NaSS).

Electro-optic heterodyne interferometer.

We propose a new configuration for using a triangle-wave signal to drive the electro-optic modulator in an electro-optic heterodyne interferometer system. The new configuration is adapted to measure the phase retardation of a wave plate and the optical rotation angle of a chiral medium. By adding optic elements, the second-harmonic component amplitude of the interferometer photodetector output signal became proportional to the phase retardation or optical rotation angle of the samples being tested.