Correction for 'Impact of lanthanide ion complexation and temperature on the chemical reactivity of ,,','-tetraoctyl diglycolamide (TODGA) with the dodecane radical cation' by Gregory P. Horne , , 2023, , 16404-16413, https://doi.org/10.
View Article and Find Full Text PDFThe impact of trivalent lanthanide ion complexation and temperature on the chemical reactivity of ,,','-tetraoctyl diglycolamide (TODGA) with the -dodecane radical cation (RH˙) has been measured by electron pulse radiolysis and evaluated by quantum mechanical calculations. Additionally, Arrhenius parameters were determined for the reaction of the non-complexed TODGA ligand with the RH˙ from 10-40 °C, giving the activation energy ( = 17.43 ± 1.
View Article and Find Full Text PDFThe octadentate hydroxypyridinone ligand 3,4,3-LI(1,2-HOPO) (abbreviated as HOPO) has been identified as a promising candidate for both chelation and -element separation technologies, two applications that require optimal performance in radiation environments. However, the radiation robustness of HOPO is currently unknown. Here, we employ a combination of time-resolved (electron pulse) and steady-state (alpha self-radiolysis) irradiation techniques to elucidate the basic chemistry of HOPO and its -element complexes in aqueous radiation environments.
View Article and Find Full Text PDFChem Commun (Camb)
October 2021
UO binds to the surface of a tripolyphosphate modified mesoporous indium tin-doped oxide electrode (ITO|P). Electrochemical studies reveal that ITO|P electrodes catalyze the 2-electron interconversion between UO and U with the P-ligand assisting in the rate-limiting proton-coupled reduction of U(V) to U(IV), based on the kinetic isotope effect (1.8).
View Article and Find Full Text PDFPhotochemical water oxidation was carried out at a mesoporous nanoparticle film composed of indium tin-doped oxide (ITO). Annealing ITO at temperatures above 250 °C affects both conducting and semiconducting properties. Impressive photoelectrochemical activity was observed at this degenerate n-type semiconductor electrode, outperforming the traditional semiconductor titanium dioxide (TiO) under the same conditions.
View Article and Find Full Text PDFWe present here the electrochemical oxidation of Am(iii) to AmVO2+ and AmVIO22+ in pH 1 nitric acid using a mesoporous tin-doped indium oxide electrode modified with a covalently attached dipyrazinylpyridine ligand. The applied potential affects the distribution of Am oxidation products. At potential 1.
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