A Comprehensive Examination of the Contaminants in Drinking Water in Public Schools in California, 2017-2022.

Objectives: Reports of unsafe school drinking water in the United States highlight the importance of ensuring school water is safe for consumption. Our objectives were to describe (1) results from our recent school drinking water sampling of 5 common contaminants, (2) school-level factors associated with exceedances of various water quality standards, and (3) recommendations.

Methods: We collected and analyzed drinking water samples from at least 3 sources in 83 schools from a representative sample of California public schools from 2017 through 2022.

Tracking reduction of water lead levels in two homes during the Flint Federal Emergency.

A Federal Emergency was declared in Flint, MI, on January 16, 2016, 18-months after a switch to Flint River source water without phosphate corrosion control. Remedial actions to resolve the corresponding lead in water crisis included reconnection to the original Lake Huron source water with orthophosphate, implementing enhanced corrosion control by dosing extra orthophosphate, a "Flush for Flint" program to help clean out loose leaded sediment from service lines and premise plumbing, and eventually lead service line replacement. Independent sampling over a period of 37 months (January 2016-February 2019) was conducted by the United States Environmental Protection Agency and Virginia Tech to evaluate possible human exposure via normal flow (∼2-3 L/min) sampling at the cold kitchen tap, and to examine the status of loose deposits from the service line and the premise plumbing via high-velocity flushing (∼12-13 L/min) from the hose bib.

NOM and alkalinity interference in trace-level hexavalent chromium analysis.

Three analytical methods were evaluated for hexavalent and trivalent chromium analyses in the presence of natural organic matter (NOM) and alkalinity. Each method was tested using a simulated tap water with 1 μg L(-1) Cr(VI) and 0.8 μg L(-1) Cr(III) and several concentrations of NOM and/or alkalinity.

Rapid free chlorine decay in the presence of Cu(OH)2: chemistry and practical implications.

A rapid reaction between free chlorine and the cupric hydroxide [Cu(OH)2] solids commonly found on pipe walls in premise plumbing can convert free chlorine to chloride and rapidly age Cu(OH)2 to tenorite (CuO). This reaction has important practical implications for maintaining free chlorine residuals in premise plumbing, commissioning of new copper pipe systems, and maintaining low levels of copper in potable water. The reaction stoichiometry between chlorine and Cu(OH)2 is consistent with formation of CuO through a metastable Cu(III) intermediate, although definitive mechanistic understanding requires future research.

Determination of total chromium in environmental water samples.

It is often desirable to quantify both dissolved Cr(VI) and total Cr in samples accurately. Various protocols are now being utilized to quantify the amount of total chromium in natural waters and each of these has possible interferences. This study describes the shortcomings of each method when particulate iron is present in a water sample, and a more rigorous digestion protocol is tested.