Dalton Trans
September 2023
Correction for ' and antiproliferative activity of organo-nickel SCS-pincer complexes on estrogen responsive MCF7 and MC4L2 breast cancer cells. Effects of amine fragment substitutions on BSA binding and cytotoxicity' by Mahboubeh Hosseini-Kharat , , 2018, , 16944-16957, https://doi.org/10.
View Article and Find Full Text PDFIntroduction: Distal Femur fractures account for 4- 6% of all femur fractures and can be challenging to treat. The aims of this study are: (1) to describe a surgical technique using a medial distal femur endosteal plate to augment the stability of standard lateral plate fixation; (2) to report the results of a case-series of acute distal femur fractures (AO/OTA Type A/ Vancouver periprosthetic fractures Type C) treated using this technique.
Methods: This study describes the surgical steps for placement of a medial endosteal plate in combination with lateral locking plate in a cadaver model using fluoroscopy guidance.
This report presents the synthesis of new mono- and dicationic NCN-Ni complexes and describes their reactivities with protic substrates. (NCN is the pincer-type ligand κ , κ , κ -2,6-(CHNMe)-CH.) Treating van Koten's trivalent complex (NCN)NiBr with AgSbF in acetonitrile gives the dicationic complex [(NCN)Ni(MeCN)], whereas the latter complex undergoes a ligand-exchange reaction with (NCN)NiBr to furnish the related monocationic complex [(NCN)Ni(Br)(MeCN)].
View Article and Find Full Text PDFDalton Trans
December 2018
A family of organonickel complexes has been prepared, fully characterized, and tested for their antiproliferative activity against estrogen-responsive human breast cancer cells (MCF7). The three SCS-type pincer ligands HL1, HL2, and HL3 and their corresponding Ni(ii) complexes NiL1, NiL2, and NiL3 have been synthesized and fully characterized, including by single crystal diffraction studies for the complexes. The complexes possess square planar geometry with two symmetrical 5-membered nickellacycles.
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