Local velocimetry and rheometric measurements are performed on three dilute micellar solutions which undergo the shear-thickening transition. The three surfactants, namely, alkyltrimethyl ammonium bromide (C(n)TAB), all belong to the same family and only differ by the length of the aliphatic chain. Simultaneous ultrasonic velocimetry and rheometry recordings provide convincing evidence for a heterogeneous flow in the shear-thickening domain.
View Article and Find Full Text PDFWe study the influence of birefringence on incoherent polarized light transport in turbid media. In particular, Mueller matrices backscattered by a diffusing medium are modified by the birefringence of the suspending phase. We study this effect both theoretically, through Monte Carlo simulations, and experimentally with a highly birefringent xanthane solution in which particles are added at various concentrations to modify its turbidity.
View Article and Find Full Text PDFWe have investigated the shear flow behavior of a classical viscoelastic equimolar wormlike micellar system made of cetyltrimethylammonium bromide and potassium bromide in the semidilute regime using mechanical and optical measurements. The experimental flow curve of this surfactant solution exhibits, above a critical shear rate, a well-defined stress plateau, characteristic of a flow of the shear-banding type. We first focus on the rheological and rheo-optical transient response of the sample after the sudden start-up of flow.
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