Understanding the origin of magnetic ordering in an undoped semiconductor with native defects is an open question, which is being explored actively in research. In this investigation, the interplay between magnetic ordering and excess induced native defects in undoped anatase TiO nanoparticles is explained using an experimental and theoretical approach. It is demonstrated that structurally disordered TiO nanoparticles with a high concentration of native defects such as titanium interstitials and oxygen vacancies are synthesized using controlled atmospheric rapid cooling (i.
View Article and Find Full Text PDFHerein, porous 1D n-p type ultra-long ZnO@Bi2O3 heterojunction nanorods have been synthesized by a solvothermal method and their complex charge transport characteristics pertaining to NO2 gas sensing properties have been investigated. The porous structure of the ZnO@Bi2O3 heterojunction nanorods assisted in achieving superior sensing properties compared to pristine ZnO nanorods. Temperature-dependent in situ electrical studies of the porous heterojunction nanorods explored the unique electron transport properties under different environments, which revealed the accumulation/depletion of electrons and charge carrier recombination leading to band bending at the metal oxide heterojunctions.
View Article and Find Full Text PDFJ Breath Res
July 2019
This work demonstrates the development of Ag@polyaniline/multi-walled carbon nanotube nanocomposite-based sensor strips and a suitable integrated electronic read-out system for the measurement of trace-level concentrations of ammonia (NH). The sensor is optimized under various operating conditions and the resulting sensor exhibited an enhanced response (32% for 2 ppm) with excellent selectivity. Stable performance was observed towards NH in the presence of high concentrations of CO (>40 000 ppm), simulated and real breath samples.
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