Biodegradation of hazardous naphthalene and cleaner production of rhamnolipids - Green approaches of pollution mitigation.

Toxic and hazardous waste poses a serious threat to human health and the environment. Green remediation technologies are required to manage such waste materials, which is a demanding and difficult task. Here, effort was made to explore the role of Pseudomonas aeruginosa SR17 in alleviating naphthalene via catabolism and simultaneously producing biosurfactant.

Adsorption of 3,4-dihydroxybenzoic acid onto hematite surface in aqueous medium: importance of position of phenolic -OH groups and understanding of the same using catechol as an auxiliary model.

A comparative adsorption kinetics, isotherms, dissolution and surface complexation of 3,4-dihydroxybenzoic acid (3,4-DHBA) and 1,2-dihydroxybenzene (catechol) at the hematite/electrolyte interface were investigated. The kinetics at pH 10 and 298.15K suggested that the adsorption behaviour of 3,4-DHBA and catechol onto hematite surface is similar and attain same equilibration time of 60 min.

Influence of chain length of alcohols on Stokes' shift dynamics in catanionic vesicles.

In this paper, we explore the effects of the chain length of simple monohydroxy alcohol (C(n)OH, 2 ≤ n ≤ 8) and benzyl alcohol (C(6)H(5)CH(2)OH) upon the fluorescence dynamics of a dipolar solute probe, coumarin 153 (C153), in vesicles formed in aqueous solutions of two oppositely charged (cationic and anionic) surfactants in the presence of 0.05 mol kg(-1) alcohol. The catanionic vesicles are composed of 70 mol % sodium dodecyl sulfate (SDS) and 30 mol % cetyltrimethylammonium bromide (CTAB).

Specific ion effects on adsorption at the solid/electrolyte interface: a probe into the concentration limit.

Adsorption of organic acid at the mineral oxide-electrolyte interface has been explored. The adsorption of 2,4-dihydroxybenzoic acid onto α-alumina illustrates that specific ion effects show up at very low salt concentration (<0.05 mM).

Ion specificity of the zeta potential of alpha-alumina, and of the adsorption of p-hydroxybenzoate at the alpha-alumina-water interface.

The influence of inorganic anions (NO(3)(-), I(-), Br(-), Cl(-), SO(4)(2-), and S(2)O(3)(2-)) and of divalent cations (Ca(2+) and Mg(2+)) on the zeta potential and on the isoelectric point of alpha-alumina in aqueous medium has been studied. The effect of the anions is highly ion specific even at salt concentrations as low as 5x10(-4) M. This unexpected finding is in line with a recent report [Böstrom et al.

Adsorption and surface complexation of trimesic acid at the alpha-alumina-electrolyte interface.

Adsorption kinetics, adsorption isotherms and surface complexation of trimesic acid onto alpha-alumina surfaces were investigated. Adsorption kinetics of trimesic acid with an initial concentration of 0.5 mM onto alpha-alumina surfaces were carried out in batch method in presence of 0.

Influence of anions on the adsorption kinetics of salicylate onto alpha-alumina in aqueous medium.

The adsorption kinetics of salicylate on alpha-alumina surfaces were studied at 25 degrees C and pH 6 in the presence of 0.05 mM concentration of different anions (Cl(-), Br(-), I(-), SCN(-), HCOO(-), CH(3)COO(-), S(2)O(2-)(3), CO(2-)(3), and SO(2-)(4)) as a function of time. The experimental data were significantly better fitted to a pseudo-second-order kinetics equation of nonlinear form in the entire time duration and are in excellent agreement with corresponding estimated values.