The radical-bearing epoxy monomer could be the ideal embodiment of multifunctionality in epoxy-based materials. This study demonstrates the potential of macroradical epoxies as surface coating materials. A diepoxide monomer derivatized with a stable nitroxide radical is polymerized with a diamine hardener under the influence of a magnetic field.
View Article and Find Full Text PDFThe power of computational modeling and simulation for establishing clear links between materials' intrinsic properties and their atomic structure has more and more increased the demand for reliable and reproducible protocols. Despite this increased demand, no one approach can provide reliable and reproducible outcomes to predict the properties of novel materials, particularly rapidly cured epoxy-resins with additives. This study introduces the first computational modeling and simulation protocol for crosslinking rapidly cured epoxy resin thermosets based on solvate ionic liquid (SIL).
View Article and Find Full Text PDFSeveral environmental and techno-economic assessments highlighted the advantage of placing polystyrene-based materials in a circular loop, from production to waste generation to product refabrication, either following the mechanical or thermochemical routes. This review provides an assortment of promising approaches to solving the dilemma of polystyrene waste. With a focus on upcycling technologies available in the last five years, the review first gives an overview of polystyrene, its chemistry, types, forms, and varied applications.
View Article and Find Full Text PDFImproving the electrical performance of macroradical epoxy thermosets to surpass the semiconductor threshold requires a comprehensive understanding of the electrical charge transport mechanisms and characteristics. In this study, we investigate the electrical properties of a non-conjugated radical thermoset in a rigid, three-dimensional (3D) motif cured under an external magnetic field. The outcomes of the four-angle analysis of the synchrotron IRM beamline provide for the first time quantitative insights into the molecular orientation at the atomic-scale level.
View Article and Find Full Text PDF