Efficient Nickel and Cobalt Recovery by Metal-Organic Framework-Based Mixed Matrix Membranes (MMM-MOFs).

Green energy transition has supposed to give a huge boost to the electric vehicle rechargeable battery market. This has generated a compelling demand for raw materials, such as cobalt and nickel, which are key common constituents in lithium-ion batteries (LIBs). However, their existing mining protocols and the concentrated localization of such ores have made cobalt and nickel mineral conundrums, and their supplies experience shortages, which threaten to slow the progress of the renewable energy transition.

Design of Multivariate Biological Metal-Organic Frameworks: Toward Mimicking Active Sites of Enzymes.

Mimicking enzymatic processes carried out by natural enzymes, which are highly efficient biocatalysts with key roles in living organisms, attracts much interest but constitutes a synthetic challenge. Biological metal-organic frameworks (bioMOFs) are potential candidates to be enzyme catalysis mimics, as they offer the possibility to combine biometals and biomolecules into open-framework porous structures capable of simulating the catalytic pockets of enzymes. In this work, we first study the catalase activity of a previously reported bioMOF, derived from the amino acid -serine, with formula {CaCu[(,)-serimox](OH)(HO)} · 39HO () (serimox = bis[(S)-serine]oxalyl diamide), which is indeed capable to mimic catalase enzymes, in charge of preventing cell oxidative damage by decomposing, efficiently, hydrogen peroxide to water and oxygen (2HO → 2 HO + O).