Orthophosphate-polyphosphate blends are commonly used to control lead release into drinking water, but little is known about how they interact with lead corrosion scale. Conventional corrosion control practice assumes that orthophosphate controls lead release by forming insoluble Pb-phosphate minerals, but this does not always occur, and under certain conditions, phosphate blends may increase lead release. Here, we used continuously-stirred tank reactors to compare orthophosphate-polyphosphate blends with orthophosphate on the basis of lead (II) carbonate dissolution and transformation at environmentally relevant phosphate concentrations.
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