Dual-mode nanophotonic upconversion oxygen sensors.

Nanophotonic biosensors capable of being excited in the NIR spectrum have applications in various sectors. Here, we develop a 980 nm-excitable nanophotonic sensor for real-time oxygen detection in both water and air by analyzing the photoluminescence lifetime and intensity using a nanocomposite of lanthanide-doped NaYF:Yb,Tm upconversion nanoparticles and a PtTFPP platinum porphyrin complex in a polystyrene matrix. Excellent overlap between the emission of the upconversion nanoparticles and the excitation band of the PtTFPP guarantees 68% efficient excitation of the PtTFPP molecules with a 980 nm NIR laser.