The peroxidase-oxidase (PO) reaction is a paradigmatic (bio)chemical system well suited to study the organization and stability of self-sustained oscillatory phases typically present in nonlinear systems. The PO reaction can be simulated by the state-of-the-art Bronnikova-Fedkina-Schaffer-Olsen model involving ten coupled ordinary differential equations. The complex and dynamically rich distribution of self-sustained oscillatory stability phases of this model was recently investigated in detail.
View Article and Find Full Text PDFWe report the discovery of non-quantum chirality in the a periodically driven Brusselator. In contrast to standard chirality from quantum contexts, this novel type of chirality is governed by rate equations, namely by purely classical equations of motion. The Brusselator chirality was found by computing high-resolution phase diagrams depicting the number of spikes, local maxima, observed in stable periodic oscillations of the Brusselator as a function of the frequency and amplitude of the external drive.
View Article and Find Full Text PDFPhys Chem Chem Phys
November 2021
Chirality is commonly associated with the spatial geometry of the atoms composing molecules, the biochemistry of living organisms, and spin properties. In sharp contrast, here we report chirality found in numerically computed stability diagrams of a chemical reaction governed by purely classical (that is, not quantum) equations, namely in a photochemically periodically perturbed ruthenium-catalyzed Belousov-Zhabotinsky reaction model. This novel chirality offers opportunities to explore hitherto unsuspected properties of purely classical chemical oscillators.
View Article and Find Full Text PDFWe report the discovery of two types of stability rings in the control parameter space of a vertical-cavity surface-emitting semiconductor laser. Stability rings are closed parameter paths in the laser control space. Inside such rings, laser stability thrives even in the presence of small parameter fluctuations.
View Article and Find Full Text PDFWe report the discovery of a regular lattice of exceptional quint points in a periodically driven oscillator, namely, in the frequency-amplitude control parameter space of a photochemically periodically perturbed ruthenium-catalyzed Belousov-Zhabotinsky reaction model. Quint points are singular boundary points where five distinct stable oscillatory phases coalesce. While spikes of the activator show a smooth and continuous variation, the spikes of the inhibitor show an intricate but regular branching into a myriad of stable phases that have fivefold contact points.
View Article and Find Full Text PDFThe peroxidase-oxidase oscillating reaction was the first (bio)chemical reaction to show chaotic behaviour. The reaction is rich in bifurcation scenarios, from period-doubling to peak-adding mixed mode oscillations. Here, we study a state-of-the-art model of the peroxidase-oxidase reaction.
View Article and Find Full Text PDFWe show that a characteristic alignment between Lyapunov vectors can be used to predict regime changes as well as regime duration in the classical Lorenz model of atmospheric convection. By combining Lyapunov vector alignment with maxima in the local expansion of bred vectors, we obtain an effective and competitive method to significantly decrease errors in the prediction of regime durations.
View Article and Find Full Text PDFIn this paper, the alignment of covariant Lyapunov vectors is used to train multi-layer perceptron ensembles in order to predict the duration of regimes in chaotic time series of Rikitake's geomagnetic dynamo model. The machine learning procedure reveals the relevance of the alignment of distinct covariant Lyapunov vectors for the predictions. To train multi-layer perceptron, we use a classification procedure that associates the number of maxima (or minima) inside regimes of motion with the duration of the corresponding regime.
View Article and Find Full Text PDFRecently, an electro-kinetic model based on a specified reaction scheme for the electro-oxidation of formic acid on platinum was reported. The model evaluated three reaction pathways towards the production of CO2: the dehydrogenation and the dehydration of formic acid, and the third and most active pathway includes fast oxidation of the formate ion. Numerical integrations showed that the model is well-suited to describe the experimental results in voltammetric and oscillatory regimes.
View Article and Find Full Text PDFPhys Chem Chem Phys
July 2018
For three complex chemical reactions displaying intricate dynamics, we assess the effectiveness of a recently proposed quantitative method to forecast bursting and large spikes, i.e. extreme events.
View Article and Find Full Text PDFThe impact of predator dormancy on the population dynamics of phytoplankton-zooplankton in freshwater ecosystems is investigated using a simple model including dormancy, a strategy to avoid extinction. In addition to recently reported chaos-mediated mixed-mode oscillations, as the carrying capacity grows, we find surprisingly wide phases of nonchaos-mediated mixed-mode oscillations to be present well before the onset of chaos in the system. Nonchaos-mediated cascades display spike-adding sequences, while chaos-mediated cascades show spike-doubling.
View Article and Find Full Text PDFWe report evidence of a surprising systematic onset of periodic patterns in very tall piles of disks deposited randomly between rigid walls. Independently of the pile width, periodic structures are always observed in monodisperse deposits containing up to 10^{7} disks. The probability density function of the lengths of disordered transient phases that precede the onset of periodicity displays an approximately exponential tail.
View Article and Find Full Text PDFTaming chaos arising from dissipative non-autonomous nonlinear systems by applying additional harmonic excitations is a reliable and widely used procedure nowadays. But the suppressory effectiveness of generic non-harmonic periodic excitations continues to be a significant challenge both to our theoretical understanding and in practical applications. Here we show how the effectiveness of generic suppressory excitations is optimally enhanced when the impulse transmitted by them (time integral over two consecutive zeros) is judiciously controlled in a not obvious way.
View Article and Find Full Text PDFRatchets are simple mechanical devices which combine spatial asymmetry and nonequilibrium to produce counterintuitive transport of particles. The operation and properties of linear ratchets have already been extensively explored. However, very little is known about circular granular ratchets, startling devices able to convert vertical vibrations into rotations of the device.
View Article and Find Full Text PDFWe argue that the alignment of Lyapunov vectors provides a quantitative criterion to predict catastrophes, i.e. the imminence of large-amplitude events in chaotic time-series of observables generated by sets of ordinary differential equations.
View Article and Find Full Text PDFChaos and regularity are routinely discriminated by using Lyapunov exponents distilled from the norm of orthogonalized Lyapunov vectors, propagated during the temporal evolution of the dynamics. Such exponents are mean-field-like averages that, for each degree of freedom, squeeze the whole temporal evolution complexity into just a single number. However, Lyapunov vectors also contain a step-by-step record of what exactly happens with the angles between stable and unstable manifolds during the whole evolution, a big-data information permanently erased by repeated orthogonalizations.
View Article and Find Full Text PDFWe report a detailed investigation of the stability of a CO2 laser with feedback as described by a six-dimensional rate-equations model which provides satisfactory agreement between numerical and experimental results. We focus on experimentally accessible parameters, like bias voltage, feedback gain, and the bandwidth of the feedback loop. The impact of decay rates and parameters controlling cavity losses are also investigated as well as control planes which imply changes of the laser physical medium.
View Article and Find Full Text PDFJ Phys Chem Lett
December 2014
We report numerical evidence of a new type of wide-ranging organization of mixed-mode oscillations (MMOs) in a model of the peroxidase-oxidase reaction, in the control parameter plane defined by the supply of the reactant NADH and the pH of the medium. In classic MMOs, the intervals of distinct periodic oscillations are always separated from each other by windows of chaos. In contrast, in the new unfolding, such windows of chaos do not exist.
View Article and Find Full Text PDFWe investigate the residual distribution of structural defects in very tall packings of disks deposited randomly in large channels. By performing simulations involving the sedimentation of up to 50 × 10(9) particles we find all deposits to consistently show a non-zero residual density of defects obeying a characteristic power-law as a function of the channel width. This remarkable finding corrects the widespread belief that the density of defects should vanish algebraically with growing height.
View Article and Find Full Text PDFWe report some regular organizations of stability phases discovered among self-sustained oscillations of a biochemical oscillator. The signature of such organizations is a nested arithmetic progression in the number of spikes of consecutive windows of periodic oscillations. In one of them, there is a main progression of windows whose consecutive number of spikes differs by one unit.
View Article and Find Full Text PDFWe report a detailed experimental study of the complex behavior of a dc low-pressure plasma discharge tube of the type commonly used in commercial illuminated signs, in a microfluidic chip recently proposed for visible analog computing, and other practical devices. Our experiments reveal a clear quasiperiodicity route to chaos, the two competing frequencies being the relaxation frequency and the plasma eigenfrequency. Based on an experimental volt-ampere characterization of the discharge, we propose a macroscopic model of the current flowing in the plasma.
View Article and Find Full Text PDFWe report the experimental discovery of a remarkable organization of the set of self-generated periodic oscillations in the parameter space of a nonlinear electronic circuit. When control parameters are suitably tuned, the wave pattern complexity of the periodic oscillations is found to increase orderly without bound. Such complex patterns emerge forming self-similar discontinuous phases that combine in an artful way to produce large discontinuous spirals of stability.
View Article and Find Full Text PDFThe investigation of regular and irregular patterns in nonlinear oscillators is an outstanding problem in physics and in all natural sciences. In general, regularity is understood as tantamount to periodicity. However, there is now a flurry of works proving the existence of "antiperiodicity", an unfamiliar type of regularity.
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