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Characterizing sorbent affinity for a target compound (described by sorbent-water distribution coefficient, K) is a necessary step in the sorbent selection and performance-testing process in the process of capturing aquatic contaminants. However, no standardized procedure exists to measure K, and studies display significant variations in set-up and performance. For per- and polyfluoroalkyl substances (PFAS), most K determinations employ batch experiments with small-scale water-sorbent mixtures, methanol-based spike of target compound(s), and analysis after assumed equilibrium, but methodological details of the above procedure differ and might cause artifacts in the determination of K.
View Article and Find Full Text PDFPer- and polyfluoroalkyl substances (PFAS) are a group of 4000+ man-made compounds of great concern due to their environmental ubiquity and adverse effects. Despite a general interest, few reliable detection tools for integrative passive sampling of PFAS in water are available. A microporous polyethylene tube with a hydrophilic-lipophilic balance sorbent could serve as a flow-resistant passive sampler for PFAS.
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