Native and alkylated polycyclic aromatic hydrocarbons (PAHs) were investigated in whole and fine grained (F < 63 μm) sediment fractions and mussels in the southern Baltic Sea. Both sediments and mussels showed spatial differences in PAH levels and profiles. In whole sediments, mean concentrations of Σ16PAHs, ΣaPAHs, and ΣPAHs reached up to 1537, 415, and 1952 ng g-1 dry weight (dw), respectively, and in mussels they reached up to 235, 143, and 325 ng g-1 dw, respectively, depending on location.
View Article and Find Full Text PDFSediment from four southern Baltic Sea locations and caged mussels were analyzed for PCBs, organochlorine pesticides and metals (Cu, Zn, Cd, Pb, Hg). In mussels, which were additionally analyzed for 16 individual PAHs, a set of biomarker responses was measured to derive an integrated biomarker response (IBR) index as a part of integrative assessment of pollution in this area. Concentrations of PCBs, ΣDDT, and metals in sediment and mussels, greatest within the Gulf of Gdańsk area, showed decreasing gradients outwards from the Gulf.
View Article and Find Full Text PDFThe concentrations of fifteen PAH compounds in samples of sediment and blue mussel tissue (Mytilus trossulus) were measured. In addition, the biliary polycyclic aromatic hydrocarbon metabolites present in flounder (Platichthys flesus) were analysed. Two methods were used in the analysis of PAH metabolites; high performance liquid chromatography (HPLC) and fixed wavelength fluorescence (FF).
View Article and Find Full Text PDFEcotoxicol Environ Saf
February 2010
Concentrations of Zn, Cu, Ni, Fe, Mn, Co and Cd in soft tissues of Macoma balthica and their extractable forms in the adjacent sediments from 15 sampling sites in the southern Baltic Sea were determined by AAS. The samples were collected during cruises of M/S Hestia and R/V Baltica in July-August 2006. In order to estimate the degree of element bioaccumulation in the molluscs with respect to their extractable forms of the associated sediments, the bioaccumulation factor (BF) was calculated.
View Article and Find Full Text PDFThe concentrations of Ag, Cd, Co, Cr, Cu, Fe, Ni, Pb, Mn and Zn in Saduria entomon and adjacent bottom sediments from the southern Baltic were determined by FAAS. In order to estimate the strength of correlations between accumulated elements in these crustaceans and surficial sediment, bioaccumulation factors (BAFs) were calculated. The results of factor analysis (FA) and the Kruskal-Wallis analysis of variance (ANOVA) clearly indicate geographical differences between the concentrations of these elements.
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