Air Quality Monitoring for Vulnerable Groups in Residential Environments Using a Multiple Hazard Gas Detector.

This paper presents a smart "e-nose" device to monitor indoor hazardous air. Indoor hazardous odor is a threat for seniors, infants, children, pregnant women, disabled residents, and patients. To overcome the limitations of using existing non-intelligent, slow-responding, deficient gas sensors, we propose a novel artificial-intelligent-based multiple hazard gas detector (MHGD) system that is mounted on a motor vehicle-based robot which can be remotely controlled.

Exploring Strategies To Bias Sequence in Natural and Synthetic Oligomers and Polymers.

Millions of years of biological evolution have driven the development of highly sophisticated molecular machinery found within living systems. These systems produce polymers such as proteins and nucleic acids with incredible fidelity and function. In nature, the precise molecular sequence is the factor that determines the function of these macromolecules.

Emergent Properties of Giant Vesicles Formed by a Polymerization-Induced Self-Assembly (PISA) Reaction.

Giant micrometer sized vesicles are of obvious interest to the natural sciences as well as engineering, having potential application in fields ranging from drug delivery to synthetic biology. Their formation often requires elaborate experimental techniques and attempts to obtain giant vesicles from chemical media in a one-pot fashion have so far led to much smaller nanoscale structures. Here we show that a tailored medium undergoing controlled radical polymerization is capable of forming giant polymer vesicles.

Unusual kinetics of poly(ethylene glycol) oxidation with cerium(IV) ions in sulfuric acid medium and implications for copolymer synthesis.

The cerium(IV)-alcohol couple in an acidic medium is an example of a redox system capable of initiating free radical polymerization. When the alcohol has a polymeric nature, the outcome of such a process is a block copolymer, a member of a class of compounds possessing many useful properties. The most common polymer with a terminal -OH group is poly(ethylene glycol) (PEG); however, the detailed mechanism of its reaction with cerium(IV) remains underexplored.

Straightforward synthesis route to polymersomes with simple molecules as precursors.

We demonstrate an easy-to-implement experimental emulsion polymerization protocol whose outcome is an amphiphilic copolymer capable of forming vesicles in an aqueous phase. The protocol does not require prior purification of chemicals or the exclusion of oxygen. Using n-butyl acrylate as the monomer, we employ a redox initiation system composed of cerium(IV) ions and poly(ethylene glycol) (PEG), optimizing the performance of this redox couple such that the reaction can be conducted in air.

Realistic parameters for simple models of the Belousov-Zhabotinsky reaction.

We use experimental results to estimate the values of parameters of simple models describing the time evolution of the Belousov-Zhabotinsky reaction proceeding in droplets surrounded by hydrocarbons. The equations with fitted parameters correctly describe the period of oscillations for a large class of experimental conditions at which the reaction is performed.