High-Density Polyethylene with In-Chain Photolyzable and Hydrolyzable Groups Enabling Recycling and Degradation.

Polyethylenes endowed with low densities of in-chain hydrolyzable and photocleavable groups can improve their circularity and potentially reduce their environmental persistency. We show with model polymers derived from acyclic diene metathesis polymerization that the simultaneous presence of both groups has no adverse effect on the polyethylene crystal structure and thermal properties. Post-polymerization Baeyer-Villiger oxidation of keto-polyethylenes from non-alternating catalytic ethylene-CO chain growth copolymerization yield high molecular weight in-chain keto-ester polyethylenes (M ≈50.

Voltammetry as a Tool to Monitor the Aggregation Behavior of a Zwitterionic Ferrocene Surfactant.

Amphiphiles are unique in their ability to self-assemble in aqueous solution into aggregates. The control of the self-organization of amphiphiles and the live monitoring of the ensuing structure changes by analytical methods are key challenges in this field. One way to gain control and to trigger the self-assembly/disassembly of amphiphiles is to introduce a redox-active constituent to the amphiphile structure, as is the case with metallosurfactants.