Environ Sci Pollut Res Int
December 2024
The wet flue gas desulfurization (WFGD) procedure results in wastewater containing a complex mixture of pollutants, including heavy metals and organic compounds, which are hardly degradable and pose significant environmental challenges. Addressing this issue, the proposed approach, incorporating waste iron shavings as a heterocatalyst within a modified Fenton process, represents a sustainable and effective solution for contaminants degrading in WFGD wastewater. Furthermore, this study aligns with the Best Available Techniques (BAT) regulations by meeting the requirement for compound oxidation-replacing the chlorine utilization with the generation of highly reactive radicals-and coagulation, which completes the treatment process.
View Article and Find Full Text PDFThis research investigated the properties of modified cementitious composites including water purification from heavy metal-zinc. A new method for characterizing the immobilization properties of tested modifiers was established. Several additions had their properties investigated: biochar (BC), active carbon (AC), nanoparticulate silica (NS), copper slag (CS), iron slag (EAFIS), crushed hazelnut shells (CHS), and lightweight sintered fly ash aggregate (LSFAA).
View Article and Find Full Text PDFIn an era of increasing environmental awareness, it is very important to work towards eliminating or at least reducing as many harmful industrial substances as possible. However, the implementation of green chemistry methods for wastewater treatment can be difficult especially due to complexity, the high cost of reagents, and the required long process time. This paper focuses on using waste iron (WI) to remove two kinds of amaranth dye commonly used in industry.
View Article and Find Full Text PDFDyes are highly toxic and persistent in the environment. Their presence in water causes environmental and social problems. Dyes must be effectively removed from the water.
View Article and Find Full Text PDFInt J Environ Res Public Health
June 2022
The impact of the ethylenediaminetetraacetic acid (EDTA) on speciation image of selected trace metals (Zn, Cd, Cu, Pb) in bottom sediments was determined. The influence on the effectiveness of metal removal of extraction multiplicity, type of metal, extraction time and concentration of EDTA were analyzed. With the increase of extraction multiplicity, the concentration of EDTA and contact time, the efficiency of trace metals leaching increased.
View Article and Find Full Text PDFWastewater from a cosmetic factory, with an initial chemical oxygen demand (COD) of 1140 mg/L, was treated using a combined light/Fe/HO process followed by biological treatment. The light/Fe/HO process, with 1000/2280 mg/L Fe/HO doses and 120 min process time, resulted in 70% COD removal, to final COD of 341 mg/L. The chemically treated wastewater was successfully subjected to biological treatment in a sequencing batch reactor (SBR), with up to 20% volume fraction in the influent, without significant deterioration of COD, nitrogen and phosphorus removal, but with possible small negative effects on polyphosphate accumulating organisms (PAOs), nitrifiers and other bacteria present in the microbial community.
View Article and Find Full Text PDFThe ZVI/HO process was applied for cosmetic wastewater treatment. Two commercial zero-valent iron (ZVI) types with different granulations were chosen: Hepure Ferrox PRB and Hepure Ferrox Target. In addition, the pH and stirring method influence on ZVI/HO process efficiency was studied.
View Article and Find Full Text PDFOne of the main challenges and unknowns during shale gas exploration is to assess the range and efficiency of hydraulic fracturing. It is also essential to assess the distribution of proppant, which keeps the fracture pathways open. Solving these problems may considerably increase the efficiency of the shale gas extraction.
View Article and Find Full Text PDFThis study aimed to describe the prevalence heavy metals (Zn, Cu, Pb, and Cd) forms in the ecosystem of the Utrata river in order to determine the mobile forms and bioavailability of metals. To extract the dissolved forms of metals in the water of the Utrata PHREEQC2 geochemical speciation model was used. The river waters show a high percentage of mobile and eco-toxic forms of Zn, Cu and Pb.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
December 2014
Advanced Oxidation Processes (AOPs), such as the Fenton, photo-Fenton and H2O2/UV processes, have been investigated for the treatment of cosmetic wastewaters that were previously coagulated by FeCl3. The Photo-Fenton process at pH 3.0 with 1000/100 mg L(-1) H2O2/Fe(2+) was the most effective (74.
View Article and Find Full Text PDFIn this study, the treatment process of three cosmetic wastewater types has been investigated. Coagulation allowed to achieve chemical oxygen demand (COD) removal of 74.6%, 37.
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