Topotactic transformation of single crystals: From perovskite to infinite-layer nickelates.

Topotactic transformations between related crystal structures are a powerful emerging route for the synthesis of novel quantum materials. Whereas most such “soft chemistry” experiments have been carried out on polycrystalline powders or thin films, the topotactic modification of single crystals, the gold standard for physical property measurements on quantum materials, has been studied only sparsely. Here, we report the topotactic reduction of LaCaNiO single crystals to LaCaNiO using CaH as the reducing agent.

Strain and vector magnetic field tuning of the anomalous phase in SrRuO.

A major area of interest in condensed matter physics is the way electrons in correlated electron materials can self-organize into ordered states, and a particularly intriguing possibility is that they spontaneously choose a preferred direction of conduction. The correlated electron metal SrRuO has an anomalous phase at low temperatures that features strong susceptibility toward anisotropic transport. This susceptibility has been thought to indicate a spontaneous anisotropy, that is, electronic order that spontaneously breaks the point-group symmetry of the lattice, allowing weak external stimuli to select the orientation of the anisotropy.

Persistent Paramagnons Deep in the Metallic Phase of Sr_{2-x}La_{x}IrO_{4}.

We have studied the magnetic excitations of electron-doped Sr_{2-x}La_{x}IrO_{4} (0≤x≤0.10) using resonant inelastic x-ray scattering at the Ir L_{3} edge. The long-range magnetic order is rapidly lost with increasing x, but two-dimensional short-range order (SRO) and dispersive magnon excitations with nearly undiminished spectral weight persist well into the metallic part of the phase diagram.

Strong increase of T(c) of Sr₂RuO₄ under both tensile and compressive strain.

A sensitive probe of unconventional order is its response to a symmetry-breaking field. To probe the proposed p(x) ± ip(y) topological superconducting state of Sr2RuO4, we have constructed an apparatus capable of applying both compressive and tensile strains of up to 0.23%.