Publications by authors named "James Roscow"

Article Synopsis
  • Adding porosity to ferroelectric ceramics can improve open circuit voltage and electrical energy through the direct piezoelectric effect but also lowers the longitudinal piezoelectric coefficient (d), limiting pore fraction options.
  • The research shows that incorporating aligned lamellar pores in (BaCa)(ZrTi)O can enhance d by 22-41% compared to denser materials.
  • This combination of higher d and lower permittivity results in significant improvements in the voltage coefficient (g), energy harvesting figure of merit (FoM), and electromechanical coupling coefficient, driven by a balance of low defect concentration and a strong internal polarizing field in the porous structure.
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Lead-free BiFeO-BaTiO (BF-BT) piezoceramics have sparked considerable interest in recent years due to their high piezoelectric performance and high Curie temperature. In this paper, we show how the addition of highly aligned porosity (between 40 and 60 vol %) improves the piezoelectric performance, sensing, and energy harvesting figures of merit in freeze-cast 0.70BiFeO-0.

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Porous and composite piezoelectric ceramics are of interest for underwater ultrasonic transducers due to their improved voltage sensitivity and acoustic matching with water, compared with their dense counterparts. Commonly, these materials are fabricated by dice-and-fill of sintered blocks of polycrystalline piezoceramic, which results in a high volume of waste. The freeze-casting technique offers a low waste and scalable alternative to the dice-and-fill method to produce porous piezoceramics with highly orientated, anisometric pores.

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Wearable electronics are becoming increasingly important for medical applications as they have revolutionized the way physiological parameters are monitored. Ferroelectric materials show spontaneous polarization below the Curie temperature, which changes with electric field, temperature, and mechanical deformation. Therefore, they have been widely used in sensor and actuator applications.

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In the past decade, the rapid development of portable electronic devices, electric vehicles, and electrical devices has stimulated extensive interest in fundamental research and the commercialization of electrochemical energy-storage systems. Biomass-derived carbon has garnered significant research attention as an efficient, inexpensive, and eco-friendly active material for energy-storage systems. Therefore, high-performance carbonaceous materials, derived from renewable sources, have been utilized as electrode materials in sodium-ion batteries and sodium-ion capacitors.

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This paper demonstrates the significant benefits of exploiting highly aligned porosity in piezoelectric and pyroelectric materials for improved energy harvesting performance. Porous lead zirconate (PZT) ceramics with aligned pore channels and varying fractions of porosity were manufactured in a water-based suspension using freeze-casting. The aligned porous PZT ceramics were characterized in detail for both piezoelectric and pyroelectric properties and their energy harvesting performance figures of merit were assessed parallel and perpendicular to the freezing direction.

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There is a growing need for high energy density capacitors in modern electric power supplies. The creation of nanocomposite systems based on one-dimensional nanofibers has shown great potential in achieving a high energy density since they can optimize the energy density by exploiting both the high permittivity of ceramic fillers and the high breakdown strength of the polymer matrix. In this paper, BaTiO nanofibers (NFs) with different aspect ratio were synthesized by a two-step hydrothermal method and the permittivity and energy storage of the P(VDF-HFP) nanocomposites were investigated.

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This work demonstrates the potential of porous BaTiO for piezoelectric sensor and energy-harvesting applications by manufacture of materials, detailed characterisation and application of new models. Ferroelectric macro-porous BaTiO ceramics for piezoelectric applications are manufactured for a range of relative densities,  = 0.30-0.

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