Laser-cum-KOH activation allows interfacial engineering of cardboard-derived carbon, tunable ionic states, and universal dye adsorption.

In this study, we demonstrate the preparation of laser-cum KOH-activated porous carbon with tunable ionic states, unique surface chemistry, and physical texture from renewable and environmentally friendly precursors (waste cardboard boxes). The adsorption performance of the engineered adsorbents is examined on the adsorption of methyl blue (MB, anionic) and methylene blue (MeB, cationic). The adsorption mechanism was determined using detailed batch adsorption, and the MB was adsorbed via the formation of ternary complexes, whereas the MeB was adsorbed through cation-π interaction.