Pd nanoparticles decorated on a porous Co(BDC-NH) MOF as an effective heterogeneous catalyst for dye reduction.

Herein, a new catalytic nanocomposite [Co(BDC-NH)-Pd NPs] composed of a Co(BDC-NH) MOF has been developed. The catalyst was prepared by modifying the synthesized porous Co(BDC-NH) MOF with decorated Pd nanoparticles. This nanocatalyst was used as a heterogeneous catalyst in the reductive degradation of organic dyes Rhodamine B and methyl orange with NaBH.

Facile synthesis of a new covalent organic nanosheet (CON-KEY1) based on polyamide links as an effective heterogeneous catalyst in C-C cross coupling reactions.

C-C coupling reactions represent a fundamental synthetic methodology widely employed in academic and industrial settings. Herein, we present a report on developing and synthesizing a heterogeneous catalyst that is environmentally compatible and has recycling capabilities. Furthermore, the utilization of this catalyst for C-C coupling reactions was explored.

Synthesis of a Au/Au NPs-PPy/l-CYs/ZIF-8 nanocomposite electrode for voltammetric determination of insulin in human blood.

In this work, a modified electrode named Au/Au NPs-PPy/l-CYs/ZIF-8 was designed and built and simultaneously doped into electropolymerized polypyrrole (PPy) film using cyclic voltammetry (CV). Scanning Electron Microscopy (SEM), Electrochemical Impedance Spectroscopy (EIS), and CV were used to characterize the composite films. The PPy-(ZIF-8) modified Au electrode was used to determine insulin using Square-Wave Voltammetry (SWV).

Pd-Coordinated Salinidol-Modified Mixed MOF: An Excellent Active Center for Efficient Nitroarenes Reduction and Selective Oxidation of Alcohols.

Selective oxidation of active and inactive alcohol substrates and reduction of nitroarenes is a highly versatile conversion that remains a challenge in controlling functionality and adjustments in metal-organic frameworks (MOFs). On the other hand, it offers an attractive opportunity to expand their applications in designing the next generation of catalysts with improved performance. Herein, a novel mixed MOF consisting of supported 2-hydroxybenzamide (mixed MOF-salinidol) has been fabricated by post-synthetic modifications of mixed MOF.

Palladium Schiff base complex-modified Cu(BDC-NH) metal-organic frameworks for C-N coupling.

In this study, the synthesis of a novel functionalized metal-organic-framework (MOF) [Cu(BDC-NH)@Schiff-base-Pd(ii)] catalyst post-synthetic modification of Cu(BDC-NH) is reported. The targeted complex was prepared by chemically attaching ,'-bis(5-formylpyrrol-2-ylmethyl) homopiperazine a Schiff base reaction followed by complexation with Pd ions. Afterwards, the synthesized solid was applied as a very effective multifunctional catalyst in C-N coupling reactions.