Cancer monitoring plays a critical role in improving patient outcomes by providing early detection, personalized treatment options, and treatment response tracking. Carbon-based electrochemical biosensors have emerged in recent years as a revolutionary technology with the potential to revolutionize cancer monitoring. These sensors are useful for clinical applications because of their high sensitivity, selectivity, rapid response, and compatibility with miniaturized equipment.
View Article and Find Full Text PDFColorectal cancer is still a major global health concern, and early detection and accurate biomarker analyses are critical to its successful management. This paper describes the design and testing of a new biosensor based on a graphene oxide (GO) nanocomposite for the exact measurement of carcinoembryonic antigen (CEA), a well-known biomarker for colorectal cancer. The current study attempted to create a highly sensitive immunosensor for sensitive measurement of CEA based on a polypropylene-imine-dendrimer (PPI) and GO nanocomposite on GCE (PPI/GO/GCE).
View Article and Find Full Text PDFPendimethalin (PND) is a herbicide that is regarded to be possibly carcinogenic to humans and toxic to the environment. Herein, we fabricated a highly sensitive DNA biosensor based on ZIF-8/Co/rGO/CN nanohybrid modification of a screen-printed carbon electrode (SPCE) to monitor PND in real samples. The layer-by-layer fabrication pathway was conducted to construct ZIF-8/Co/rGO/CN/ds-DNA/SPCE biosensor.
View Article and Find Full Text PDFp_Aminophenol, namely 4-aminophenol (4-AP), is an aromatic compound including hydroxyl and amino groups contiguous together on the benzene ring, which are suitable chemically reactive, amphoteric, and alleviating agents in nature. Amino phenols are appropriate precursors for synthesizing oxazoles and oxazines. However, since the toxicity of aniline and phenol can harm human and herbal organs, it is essential to improve a reliable technique for the determination of even a trace amount of amino phenols, as well as elimination or (bio)degradation/photodegradation of it to protect both the environment and people's health.
View Article and Find Full Text PDFThe effectual utilization of heterogeneous catalysts from nano sources through chemical moderation for the α-aminomethylcarboxylation of alkenes with carbon dioxide and amines is an attractive area to study. Dendritic fibrous nanosilica (DFNS) is a cost-effective, resistant, plenteous, and reproducible source with dandelion-like fibrous anatomy. The present paper is a report on an easy method to provide a family of new DFNS-supported dendritic imidazolium IL/Ru(ii) heterogeneous catalysts DFNS/IL/Ru (1-3) with high ionic density from DFNS.
View Article and Find Full Text PDFAzo dyes as widely applied food colorants are popular for their stability and affordability. On the other hand, many of these dyes can have harmful impacts on living organs, which underscores the need to control the content of this group of dyes in food. Among the various analytical approaches for detecting the azo dyes, special attention has been paid to electro-analytical techniques for reasons such as admirable sensitivity, excellent selectivity, reproducibility, miniaturization, green nature, low cost, less time to prepare and detect of specimens and the ability to modify the electrode.
View Article and Find Full Text PDFFood Chem Toxicol
April 2022
Synthetic azo dyes are widely used in a variety of industries, but many of them pose a risk to human health, particularly when consumed in large quantities. As a result, their existence in products should be closely monitored. D&C red 33 and Patent Blue V are mostly used in cosmetics, especially in toothpaste and mouthwashes.
View Article and Find Full Text PDFDrug efficiency can be considerably boosted while adverse effects can be reduced by precisely monitoring the concentration of anti-cancer drugs. Thus, one of the most important parameters for human health is the monitoring and detection of anticancer drugs during chemotherapy treatment. Herein, a glassy carbon electrode (GCE) was modified by Pt- and Pd-incorporated ZnO nanoparticles-decorated single-wall carbon nanotubes (Pt-Pd-ZnO/SWCNTs) nanocomposites, and ds-DNA (Calf Thymus) that was a biological recognition element, and it was aimed to be utilized as an ultrasensitive and effective electroanalytical biosensor for idarubicin (IDR) monitoring.
View Article and Find Full Text PDFIn the present study, gold nanoparticles were locally well-decorated on the surface of TiO using the tungstophosphoric acid (HPW), as UV-switchable reducing intermediate linkers. The prepared Au NPs/HPW/TiO nanostructure was characterized using FTIR, XRD, EDS, SEM and TEM, which confirmed the successful attachment of quasi-spherical Au NPs in the range of 20-30 nm on the surface of HPW modified TiO. Also, the FTIR results show that the Au NPs were binded to TiO through the terminal the oxygen atoms HPW.
View Article and Find Full Text PDFOrganophosphorus insecticide fenamiphos (FEN) is utilized to control the detrimental nematode pests. In this report, a novel molecular imprinted electrochemical sensor for insecticide FEN detection was prepared. The molecular imprinted sensor was prepared based on CoO nanowire and core-shell CoO@MOF-74 nanocomposite.
View Article and Find Full Text PDFIn the present study, a novel 1-butyl-3-methylimidazolium bromide (BmImBr) impregnated chitosan beads were prepared and characterized using different methods, including XRD, FT-IR, EDX, SEM and BET. The FTIR analysis revealed that the BmImBr was successfully conjugated with the chitosan in the beads structure. The prepared beads were used as an efficient sorbent for the fast removal of methylene blue, as cationic dye model, from aqueous solution, whereas just 25 min was required to reach 86% removal efficiency.
View Article and Find Full Text PDFIn this study, a novel carbon nanotube (CNT) based nanocatalyst (Ni@Pd/CNT) was synthesized by modifying CNTs using Ni@Pd core-shell nanoparticles (NPs). Ni@Pd/CNT was used in catalytic carbonylative cross-coupling between 4-iodoanisole and phenylboronic acid. The Ni@Pd NPs possessed a magnetic nickel (Ni) core with a palladium (Pd) structural composite shell.
View Article and Find Full Text PDFHigh-density and well-aligned ZnO-ZnS core-shell nanocone arrays were synthesized on fluorine-doped tin oxide glass substrate using a facile and cost-effective two-step approach. In this synthetic process, the ZnO nanocones act as the template and provide Zn2+ ions for the ZnS shell formation. The photoluminescence spectrum indicates remarkably enhanced luminescence intensity and a small redshift in the UV region, which can be associated with the strain caused by the lattice mismatch between ZnO and ZnS.
View Article and Find Full Text PDFAmong the wide range of renewable energy sources, the ever-increasing demand for electricity storage represents an emerging challenge. Utilizing carbon nanotubes (CNTs) for energy storage is closely being scrutinized due to the promising performance on top of their extraordinary features. In this work, well-aligned multilayer carbon nanotubes were successfully synthesized on a porous silicon (PSi) substrate in a fast process using renewable natural essential oil via chemical vapor deposition (CVD).
View Article and Find Full Text PDFWell-dispersed fish gelatin-based nanocomposites were prepared by adding ZnO nanorods (NRs) as fillers to aqueous gelatin. The effects of ZnO NR fillers on the mechanical, optical, and electrical properties of fish gelatin bio-nanocomposite films were investigated. Results showed an increase in Young's modulus and tensile strength of 42% and 25% for nanocomposites incorporated with 5% ZnO NRs, respectively, compared with unfilled gelatin-based films.
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