Genetic algorithm for obtaining potential energy curve of diatomic molecules based on dispersed fluorescence spectra.

The method for reconstruction of an adiabatic potential energy curve from experimental dispersed fluorescence spectra has been developed. The novelty of the method relies on a unique approach of simultaneous use of [Formula: see text] and [Formula: see text] parts of the spectrum. The method is based on the Genetic Algorithm (GA) procedure and determines potential energy curve integrally, below and above the dissociation energy limit.