Publications by authors named "Jairo Tronto"

Integrating agricultural, chemical, and technological knowledge is crucial for developing bio-nanotechnologies to improve agricultural production. This study explores the innovative use of biopolymeric coatings, based on sodium alginate and sodium alginate + Laponite® (nanoclay), containing biostimulants (tryptophol and thymol) or not, on garlic cloves. These coatings were analyzed using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR-ATR), and scanning electron microscopy (SEM).

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Organic-inorganic hybrid materials have a range of applications due to their unique properties. Their application in agriculture brings alternatives for the controlled release of nutrients in the soil, the seed coating, the transport of herbicides, and the treatment of plant diseases. The present study aimed to investigate the use of fungicides incorporated into hybrid membranes formed by synthetic hectorite (LAPONITE®) and polymers in the pre-treatment of garlic bulbils exposed to the pathogen , which causes white rot.

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Mesoporous carbon (MC) derived from cassava starch was used to remove Acid Blue 113 azo dye from aqueous solutions. The influence of temperature, pH, ionic strength, and the adsorbent dose was investigated in a set of batch experiments. Experimental data showed that Acid Blue 113 adsorption was higher in the acid pH range than in the alkaline one, that dye adsorption increases when the ionic strength and temperature increase, and that adsorption results presented a good correlation with the Langmuir isotherm model.

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Auxins are a class of organic substances known as plant-growth regulators, which act on plant physiology, promoting its full development. However, due to the great instability of these substances among the diversity of crops and cultivation environments, it is necessary to seek more efficient modes of application, which lead to a homogeneous distribution and promote a sustained release according to the plants demand. Seed coating, using films containing a biodegradable polymer and auxins intercalated into layered compounds, emerges as a very promising approach to a new form of growth regulator application.

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Phosphorus (P) is a nutrient necessary for agricultural production and a potential originator for eutrophication in water bodies, resulting in qualitative changes; it may also affect the aquatic ecosystem and human health. In addition, as a finite resource, the importance of studying strategies to remove it from water is evident, thus making possible its recycling. Many studies have used powdered materials, including biochars, for P water decontamination; however, the difficulty of separating and collecting these materials from water after adsorption may be difficult.

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Increases in agricultural productivity associated to the crescent use of finite reserves of phosphorus improved the demand for ways to recycle and reuse this nutrient. Biochars, after doping processes, seem to be an alternative to mitigate the large use of P reserves. Sugarcane straw and poultry manure were submerged in an MgCl solution in a 1:10 solid/liquid ratio and subsequently pyrolyzed at 350 and 650 °C producing biochar.

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This work showed a flow system designed with solenoid valves for preconcentration of fluoride using SPADNS method in water samples. The analyte was preconcentrated in a mini-column coated with Layered Double Hydroxides (LDH) used as adsorbent. Then, the fluoride ions were eluted with 0.

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The production of biodegradable plastic materials using natural resources has aroused increased attention due to environmental concerns. This study aimed to manufacture novel, commercially feasible, biodegradable sheets by flat die extrusion-calendering process produced with thermoplastic starch/plasticized cellulose acetate (TPS/PCA) and thermoplastic starch/plasticized cellulose acetate/poly (butylene adipate-co-terephthalate) (TPS/PCA/PBAT) blends, and to investigate the effects of composition and processing conditions, morphological characteristics, and thermal properties. The results showed that TPS/PCA and TPS/PCA/PBAT biodegradable sheets properties were highly dependent upon both composition and processing temperature.

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Sorption of aspartic and glutamic aminoacids by regeneration of calcined hydrotalcite is reported. Hydrotalcite was synthesized by coprecipitation and calcined at 773 K. Sorption experiments were performed at 298 K and 310 K, and the results reveal that at low aminoacids equilibrium concentrations, intercalation of hydroxyl anions takes place while at high equilibrium concentrations, the sorption process occur by means re-hydration and aminoacids intercalation of hydrotalcite.

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Zn(II)-Cr(III)-LDHs (layered double hydroxides) containing sulfated or sulfonated surfactants as the interlamellar anion were synthesized by the coprecipitation method. The syntheses were conducted under various different experimental conditions, such as the Zn : Cr ratio, pH, and aging time. In each of the prepared materials, unlike previously reported data, the interlayer anion arrangement did not change, being consistent with a perpendicular monolayer.

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