Methodologies toward Efficient and Stable Cesium Lead Halide Perovskite-Based Solar Cells.

In an attempt to replace thermally vulnerable organic perovskites, considerable research effort has recently been focused on the development of all-inorganic perovskites in the field of photovoltaics. The preceding studies demonstrated that cesium lead halide perovskites are promising candidates for thermally stable and efficient solar cell materials. Here, the recent progress in cesium lead halide perovskite-based solar cells is summarized.

Halide Perovskite Nanopillar Photodetector.

Numerous studies have reported the use of halide perovskites as highly functional light-harvesting materials. The development of optimized compositions and deposition approaches has led to impressive improvements; however, no noticeable breakthrough in performance has been observed for these materials recently. Here, a breakthrough that enables the fabrication of vertically grown halide perovskite (VGHP) nanopillar photodetectors via a nanoimprinting crystallization technique is demonstrated.

Thermodynamically self-organized hole transport layers for high-efficiency inverted-planar perovskite solar cells.

Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is a popular and promising hole transport material for making efficient inverted-planar perovskite solar cells (IP-PSCs). However, the mismatch between the work function of conventional PEDOT:PSS and the valence band maximum of perovskite materials is still a challenge for efficient hole extraction. Here, we report systematic studies on the work-function modification and thermodynamic morphological evolution of PEDOT:PSS films by tuning the PSS/PEDOT ratio, along with its effects on the photovoltaic responses of IP-PSCs.

Unveiling the Crystal Formation of Cesium Lead Mixed-Halide Perovskites for Efficient and Stable Solar Cells.

Thermal instability of organic-inorganic hybrid perovskites will be an inevitable hurdle for commercialization. Recently, all-inorganic cesium lead halide perovskites, in particular, CsPbIBr, have emerged as thermally stable and efficient photovoltaic light absorbers. However, the fundamental properties of this material have not been studied in detail.

Potassium Incorporation for Enhanced Performance and Stability of Fully Inorganic Cesium Lead Halide Perovskite Solar Cells.

Thermally unstable nature of hybrid organic-inorganic perovskites has been a major obstacle to fabricating the long-term operational device. A cesium lead halide perovskite has been suggested as an alternative light absorber, due to its superb thermal stability. However, the phase instability and poor performance are hindering the further progress.