Mixed adsorption layers properties made by two organic substances in which 1-decanesulfonic acid sodium salt undergoes physical adsorption and tetramethylthoiurea (TMTU) chemical adsorption in 1M NaClO4 on the mercury electrode are described. Based on differential capacity data - potential curves obtained at mercury electrode the double layers TMTU adsorption parameters were calculated whereas the adsorption constants were derived from pressure data as a function of electrode charge density and TMTU's bulk concentration. The interaction parameters point to weak repulsive interaction between the adsorbed TMTU molecules.
View Article and Find Full Text PDFThe electrosorption behavior of tetramethylthiourea (TMTU) on a mercury electrode from 1.0, 0.5, and 0.
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