Determination of interphase line tension in Langmuir films.

A Langmuir film is a molecularly thin film on the surface of a fluid; we study the evolution of a Langmuir film with two coexisting fluid phases driven by an interphase line tension and damped by the viscous drag of the underlying subfluid. Experimentally, we study a 4{'} -8-alkyl[1, 1{'} -biphenyl]-4-carbonitrile (8CB) Langmuir film via digitally imaged Brewster angle microscopy in a four-roll mill setup which applies a transient strain and images the response. When a compact domain is stretched by the imposed strain, it first assumes a bola shape with two tear-drop shaped reservoirs connected by a thin tether which then slowly relaxes to a circular domain which minimizes the interfacial energy of the system.