Iron functionalized silica particles as an ingenious sorbent for removal of fluoride from water.

The paucity of safe drinking water remains a global concern. Fluoride is a pollutant prevalent in groundwater that has adverse health effects. To resolve this concern, we devised a silica-based defluoridation sorbent from pumice rock obtained from the Paka volcano in Baringo County, Kenya.

Evaluation of copper speciation in model solutions of humic acid by mini-columns packed with Chelex-100 and new chelating agents: application to speciation of selected heavy metals in environmental water samples.

A solid-phase extraction procedure using mini-columns packed with Chelex-100 and two new chelating agents based on poly(vinyl chloride) functionalized with 3-ferrocenyl-3-hydroxydithioacrylic acid and N,N'-[1,1'-dithiobis(ethylene)]-bis(salicylideneimine) (H(2)sales) loaded on microcrystalline naphthalene, is reported. The columns were used to separate labile copper fractions in model solutions and in real samples with subsequent determination using electrothermal atomic absorption spectrometry (ETAAS). Various model solutions containing 20 microg L(-1) of Cu(2+) and 0.

Speciation studies of nickel and chromium in wastewater from an electroplating plant.

A speciation scheme involving the use of flame atomic absorption spectrometry (FAAS) and differential pulse adsorptive cathodic stripping voltammetry (DPAdCSV) techniques was applied to studies of nickel and chromium in wastewater from a nickel-chrome electroplating plant. Dimethylglyoxime (DMG) and diethylenetriaminepentaacetic acid (DTPA) were employed as complexing agents for adsorptive voltammetric determination of Ni and Cr, respectively. Cr(III) and Cr(VI) were determined by exploiting differences in their reactivity towards DTPA at HMDE.