Model for the Shape of the Relaxation Spectrum in Glass Formers.

Traditionally the broadness of the spectrum of the relaxation times observed in glass-forming materials has been rationalized by local heterogeneity, where a variety of atomistic environments leads to spectrum of single-exponential relaxation responses. However, the assumption of heterogeneity can break down when tested against the shape of the relaxation spectrum. An alternative homogeneous scenario assumes that the relaxation is inherently multiexponential.

Temperature and pressure dependence of the alpha relaxation in ortho-terphenyl.

Molecular dynamics (MD) simulations of ortho-terphenyl using an all-atom model with the optimized potentials for liquid simulations (OPLS) force field were performed both in the high temperature Arrhenian region and at lower temperatures that include the onset of the super-Arrhenian region. From the MD simulations, the internal energy of both the equilibrium liquid and crystal was determined from 300 K to 600 K and at pressures from 0.1 MPa to 1 GPa.