The B 1Pi state of NaCs: high resolution laser induced fluorescence spectroscopy and potential construction.

The lowest (1)Pi state of the NaCs molecule, the B(1)(1)Pi state, was studied using a dye laser for inducing fluorescence that was resolved by a high resolution Fourier-transform spectrometer. The presence of argon buffer gas yielded rich rotational relaxation spectra allowing to enlarge the data set for the B(1)(1)Pi state, to obtain Lambda-splittings and to reveal numerous local perturbations. 543 weakly perturbed energy levels for rotational quantum numbers from J(')=5 to 168 and vibrational quantum numbers from v(')=0 to 25, which cover about 87% of the potential well depth, were used for a direct pointwise fit of the potential energy curve applying the inverted perturbation approach method.

Experimental and theoretical studies of lambda doublings and permanent electric dipoles in the low-lying 1pi states of NaCs.

We present experimental data on the electric permanent dipole moments d(v',J') and lambda splittings (q factors) in the quasidegenerate (3) 1pi(e/f) state of the NaCs molecule over a wide range of the vibrational (v') and rotational (J') quantum numbers by using the combination of dc Stark mixing and electric radio frequency-optical double resonance methods. Within the experimental (3) 1pi state v' ranged from v' = 0 to 34, q values exhibited a pronounced decrease from 7.91x10(-6) to 0.

High resolution spectroscopy and potential determination of the (3)1Pi state of NaCs.

The (3)(1)Pi state of the NaCs molecule was studied by high resolution Fourier-transform spectroscopy. The (3)(1)Pi-->X (1)Sigma(+) laser induced fluorescence was excited by an Ar(+) ion laser or by a single-mode frequency-doubled cw Nd:YAG laser. The presence of argon buffer gas yielded rich rotational relaxation spectra allowing to enlarge the data set for the (3)(1)Pi state term values, as well as to observe Lambda splittings in a wide range of vibrational (v(')) and rotational (J(')) quantum numbers.