Site-selective -arylations of glycoside-derived diols have been achieved by couplings with bromoarenes upon irradiation with blue LEDs in the presence of an iridium photocatalyst and a nickel complex. The use of hexamethylenetetramine (hexamine) in place of quinuclidine, along with the application of a methoxy-substituted 2,2'-bipyridine ligand, provided improvements in yield for this relatively challenging substrate class. Selective arylation took place at the less sterically hindered OH group, as determined by the substitution pattern and configuration of the glycoside substrate.
View Article and Find Full Text PDFJ Nutr Educ Behav
November 2024
The change in policy that allowed Supplemental Nutrition Assistance Program recipients to redeem their benefits online during the coronavirus disease 2019 pandemic highlighted the potential role of nutrition education programs in facilitating the purchase of healthy, economical food online. The objective of this exploratory qualitative study was to understand the education provided by nutrition educators on online grocery shopping and educators' perspectives on education needs and ways that healthy purchases can be encouraged online. Interviews revealed topics that can be included in in-person education on online shopping, insights for online nutrition education, and promotion strategies for encouraging healthy purchases by low-income shoppers online.
View Article and Find Full Text PDFThere is some evidence that the river migration success of Atlantic salmon smolts, on their first migration to sea, varies both spatially and temporally. However, we have only a poor understanding of what may be driving this variation. In this study, we used acoustic telemetry to quantify the spatial and temporal variations in river migration success in Atlantic salmon smolts on their first migration to sea.
View Article and Find Full Text PDFObjective: To report the technique and the outcome for the repair of pelvic fractures in cats using external skeletal fixation (ESF).
Study Design: Retrospective case series.
Animals: Client-owned cats (n = 125).