Progress Toward High Power Output in Thermionic Energy Converters.

Thermionic energy converters are solid-state heat engines that have the potential to produce electricity with efficiencies of over 30% and area-specific power densities of 100 Wcm. Despite this prospect, no prototypes reported in the literature have achieved true efficiencies close to this target, and many of the most recent investigations report power densities on the order of mWcm or less. These discrepancies stem in part from the low-temperature (<1300 K) test conditions used to evaluate these devices, the large vacuum gap distances (25-100 µm) employed by these devices, and material challenges related to these devices' electrodes.

Micron-gap spacers with ultrahigh thermal resistance and mechanical robustness for direct energy conversion.

In thermionic energy converters, the absolute efficiency can be increased up to 40% if space-charge losses are eliminated by using a sub-10-µm gap between the electrodes. One practical way to achieve such small gaps over large device areas is to use a stiff and thermally insulating spacer between the two electrodes. We report on the design, fabrication and characterization of thin-film alumina-based spacers that provided robust 3-8 μm gaps between planar substrates and had effective thermal conductivities less than those of aerogels.

Engineering Ultra-Low Work Function of Graphene.

Low work function materials are critical for energy conversion and electron emission applications. Here, we demonstrate for the first time that an ultralow work function graphene is achieved by combining electrostatic gating with a Cs/O surface coating. A simple device is built from large-area monolayer graphene grown by chemical vapor deposition, transferred onto 20 nm HfO2 on Si, enabling high electric fields capacitive charge accumulation in the graphene.

Photon-enhanced thermionic emission from heterostructures with low interface recombination.

Photon-enhanced thermionic emission is a method of solar-energy conversion that promises to combine photon and thermal processes into a single mechanism, overcoming fundamental limits on the efficiency of photovoltaic cells. Photon-enhanced thermionic emission relies on vacuum emission of photoexcited electrons that are in thermal equilibrium with a semiconductor lattice, avoiding challenging non-equilibrium requirements and exotic material properties. However, although previous work demonstrated the photon-enhanced thermionic emission effect, efficiency has until now remained very low.