Infrared evidence of three distinct acidic hydroxyls in defect-free HY faujasite.

Trimethylamine (TMA) and ammonia (NH(3)) were coadsorbed over a free extraframework aluminum (EFAL) HY zeolite, which allowed us to distinguish at least three different acidic hydroxyls in the faujasite structure.

Trimethylamine as a probe molecule to differentiate acid sites in Y-FAU zeolite: FTIR study.

In heterogeneous catalysis acidity has a very important influence on activity and selectivity: correct determination of acidic properties is a base to improve industrial processes. The aim of this work was to study trimethylamine (TMA) as a probe molecule able to distinguish between the different Brønsted acid sites in zeolitic frameworks. Our work mainly focused on faujasite-type zeolites because the HY zeolite is one of the most used acidic catalysts in industrial processes.

FTIR spectroscopic study of low temperature NO adsorption and NO + O2 coadsorption on H-ZSM-5.

Adsorption of NO and coadsorption of NO and O2 on H-ZSM-5 have been studied at low and room temperature by means of FTIR spectroscopy. For better interpretation of the spectra, experiments involving isotopic labeled molecules have been performed. Low temperature adsorption of NO on H-ZSM-5 results initially in formation of NO which is H-bonded to the zeolite acidic hydroxyls.