Light-Assisted Catalysis and the Dynamic Nature of Surface Species in the Reverse Water Gas Shift Reaction over Cu/γ-AlO.

The reverse water gas shift (RWGS) reaction converts CO and H into CO and water. We investigated Cu/γ-AlO catalysts in both thermally driven and light-assisted RWGS reactions using visible light. When driven by combined visible light and thermal energy, the CO conversion rates were lower than in the dark.

A coating design to rule them all: asymmetric Fabry-Perot resonators with diverse optical response based on Au films with high-temperature sensitivity.

Thermal annealing of thin metal films induces morphology changes that have a dramatic effect in the optical properties. Here we propose an asymmetric Fabry-Perot resonator consisting of a top metal film, a dielectric spacer, and a bottom metal mirror that can display a diverse infrared response. Thermally induced morphology changes result in large reflectivity variations within a limited temperature range following the top film transition between conductive, highly lossy, and transparent regimes.

Quantifying Shape Transition in Anisotropic Plasmonic Nanoparticles through Geometric Inversion. Application to Gold Bipyramids.

Unraveling the nuanced interplay between the morphology and the optical properties of plasmonic nanoparticles is crucial for targeted applications. Managing the relationship becomes significantly complex when dealing with anisotropic nanoparticles that defy a simple description using parameters like length, width, or aspect ratio. This complexity requires computationally intensive numerical modeling and advanced imaging techniques.

Reverse engineering of e-beam deposited optical filters based on multi-sample photometric and ellipsometric data.

A post-production characterization approach based on spectral photometric and ellipsometric data related to a specially prepared set of samples is proposed. Single-layer (SL) and multilayer (ML) sets of samples presenting building blocks of the final sample were measured ex-situ, and reliable thicknesses and refractive indices of the final ML were determined. Different characterization strategies based on ex-situ measurements of the final ML sample were tried, reliability of their results was compared, and the best characterization approach for practical use, when preparation of the mentioned set of samples would be a luxury, is proposed.

Green Nanocoatings Prepared by Crosslinking Self-Assembled Fatty Acids on Metals.

Self-assembled monolayers (SAMs) are an important element of modern nanotechnology and surface functionalization. However, their application is still limited because they are easily removed from the surface of the object in corrosive environments. Crosslinking would make SAMs more resistant to the corrosive environment they are exposed to.