Publications by authors named "J Rodriguez-Carvajal"

The mathematical structure, description and classification of magnetic space groups is briefly reviewed, with special emphasis on the recently proposed notation, the so-called UNI symbols [Campbell et al. (2022). Acta Cryst.

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In recent decades, sustained theoretical and software developments have clearly established that representation analysis and magnetic symmetry groups are complementary concepts that should be used together in the investigation and description of magnetic structures. Historically, they were considered alternative approaches, but currently, magnetic space groups and magnetic superspace groups can be routinely used together with representation analysis, aided by state-of-the-art software tools. After exploring the historical antagonism between these two approaches, we emphasize the significant advancements made in understanding and formally describing magnetic structures by embracing their combined use.

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A report from the International Union of Crystallography Commission on Magnetic Structures outlining the recommendations for communicating commensurate magnetic structures.

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The two commonly used systems of magnetic space-group (MSG) symbols, with accompanying numbers and settings, are those of Belov-Neronova-Smirnova (BNS) and Opechowski-Guccione (OG). The symbols from both systems have been used for several decades now. Both have advantages and disadvantages.

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This study presents the influence of polymorphism on the magnetic properties of CoTeO. This compound with a spinel-like structure [Co][CoTe]O was synthesized into two polymorphs: one disordered within a cubic 3̅ structure, where Co and Te ions are randomly distributed on the octahedral B sites [the disordered polymorph can also be presented as an inverse spinel of the formula Co(CoTe)O] and the other ordered with a cubic 432 structure where Co and Te ions are ordered on the B sites. The macroscopic magnetic measurements showed that both polymorphs present a ferrimagnetic ordering, below ∼40 K, and a second transition is also observed at 27 K for the ordered polymorph.

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